Electronic requirements for macropolyhedral boranes

ED Jemmis, MM Balakrishnarajan… - Chemical …, 2002 - ACS Publications
Among several theoretical tools available for investigating the molecular structure, there is
always a balance between simplicity and reliability. While detailed electronic structure …

Chemistry of nickel and iron bis (dicarbollides). A review

IB Sivaev, VI Bregadze - Journal of Organometallic Chemistry, 2000 - Elsevier
Chemistry of nickel and iron bis(dicarbollides). A review - ScienceDirect Skip to main contentSkip
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Stable (long-bonded) dimers via the quantitative self-association of different cationic, anionic, and uncharged π-radicals: Structures, energetics, and optical transitions

JM Lü, SV Rosokha, JK Kochi - Journal of the American Chemical …, 2003 - ACS Publications
Unusual dimers with wide interplanar separations, that is, very long bonds with d D≈ 3.05 Å,
are common to the spontaneous self-association of various organic π-radicals in solution …

Continuum of outer-and inner-sphere mechanisms for organic electron transfer. Steric modulation of the precursor complex in paramagnetic (ion-radical) self …

SV Rosokha, JK Kochi - Journal of the American Chemical …, 2007 - ACS Publications
Transient 1: 1 precursor complexes for intermolecular self-exchange between various
organic electron donors (D) and their paramagnetic cation radicals (D+•), as well as …

The modulating possibilities of dicarbollide clusters: Optimizing the Kharasch catalysts

O Tutusaus, C Viñas, R Núñez, F Teixidor… - Journal of the …, 2003 - ACS Publications
The Modulating Possibilities of Dicarbollide Clusters: Optimizing the Kharasch Catalysts |
Journal of the American Chemical Society ACS ACS Publications C&EN CAS Find my institution …

[HTML][HTML] Charge-compensated derivatives of nido-carborane

MY Stogniy, SA Anufriev, IB Sivaev - Inorganics, 2023 - mdpi.com
This review summarizes data on the main types of charge-compensated nido-carborane
derivatives. Compared with organic analogs, onium derivatives of nido-carborane have …

[HTML][HTML] Bis (Dicarbollide) Complexes of Transition Metals: How Substituents in Dicarbollide Ligands Affect the Geometry and Properties of the Complexes

IB Sivaev - Molecules, 2024 - mdpi.com
The interaction between different types of substituents in dicarbollide ligands and their
influence on the stabilization of various rotational conformers (rotamers) of transition metal …

Synthesis of novel zwitterionic nido-carborane-containing derivatives of cysteine and methionine

AA Telegina, DA Gruzdev, MA Ezhikova… - Russian Chemical …, 2024 - Springer
Abstract Alkylation of 9-methylthio-nido-carborane under the action of the corresponding
iodo derivatives of alanine and homoalanine furnished new (nido-carboran-9-yl) derivatives …

Mononuclear metallacarboranes of groups 6–10 metals: Analogues of metallocenes: Electrochemical and X-ray structural aspects

M Corsini, FF de Biani, P Zanello - Coordination chemistry reviews, 2006 - Elsevier
Metallacarboranes containing carborane ligands possessing a pentagonal open face can
coordinate metal atoms in a η5-manner quite similar to the cyclopentadienyl monoanion …

(Tetramethylcyclobutadiene) cobalt complexes with monoanionic carborane ligands [9-L-7, 8-C2B9H10]−(L= SMe2, NMe3 and py)

VI Meshcheryakov, PS Kitaev, KA Lyssenko… - Journal of …, 2005 - Elsevier
nido-Carborane 9-NMe3-7, 8-C2B9H11 (2c) was synthesized by CuSO4 oxidation of anion
[7, 8-C2B9H12]− in the presence of [Me3NH]+ in aqueous ammonia. Improved procedures …