Symmetry strategies for high performance lanthanide-based single-molecule magnets

JL Liu, YC Chen, ML Tong - Chemical Society Reviews, 2018 - pubs.rsc.org
Toward promising candidates of quantum information processing, the rapid development of
lanthanide-based single-molecule magnets (Ln-SMMs) highlights design strategies in …

Understanding the magnetic anisotropy toward single-ion magnets

YS Meng, SD Jiang, BW Wang… - Accounts of chemical …, 2016 - ACS Publications
Conspectus Single-molecule magnets (SMMs) can retain their magnetization status
preferentially after removal of the magnetic field below a certain temperature. The unique …

Strategies toward high-temperature lanthanide-based single-molecule magnets

L Ungur, LF Chibotaru - Inorganic Chemistry, 2016 - ACS Publications
Lanthanide-based single-molecule magnets are leading materials for achieving
magnetization blocking at the level of one molecule. In this paper, we examine the physical …

Review of purely 4f and mixed-metal nd-4f single-molecule magnets containing only one lanthanide ion

HLC Feltham, S Brooker - Coordination Chemistry Reviews, 2014 - Elsevier
A very basic tutorial-style introduction to Single-Molecule Magnetism, intended for a general
chemistry audience, is provided. This is followed by a review of the synthesis, structures and …

Ab initio crystal field for lanthanides

L Ungur, LF Chibotaru - Chemistry–A European Journal, 2017 - Wiley Online Library
An ab initio methodology for the first‐principle derivation of crystal‐field (CF) parameters for
lanthanides is described. The methodology is applied to the analysis of CF parameters in …

Magnetic relaxation pathways in lanthanide single-molecule magnets

RJ Blagg, L Ungur, F Tuna, J Speak, P Comar… - Nature …, 2013 - nature.com
Single-molecule magnets are compounds that exhibit magnetic bistability caused by an
energy barrier for the reversal of magnetization (relaxation). Lanthanide compounds are …

An electrostatic model for the determination of magnetic anisotropy in dysprosium complexes

NF Chilton, D Collison, EJL McInnes… - Nature …, 2013 - nature.com
Understanding the anisotropic electronic structure of lanthanide complexes is important in
areas as diverse as magnetic resonance imaging, luminescent cell labelling and quantum …

Spin states, vibrations and spin relaxation in molecular nanomagnets and spin qubits: a critical perspective

L Escalera-Moreno, JJ Baldoví, A Gaita-Arino… - Chemical …, 2018 - pubs.rsc.org
Very recently the closely related fields of molecular spin qubits, single ion magnets and
single atom magnets have been shaken by unexpected results. We have witnessed a jump …

Large magnetic anisotropy in mononuclear metal complexes

S Gómez-Coca, D Aravena, R Morales… - Coordination Chemistry …, 2015 - Elsevier
This review examines mononuclear metal complexes with high magnetic anisotropy and the
theoretical approaches used to rationalize their magnetic properties. Electronic structure …

Uncommon lanthanide ions in purely 4f Single Molecule Magnets

F Pointillart, O Cador, B Le Guennic… - Coordination Chemistry …, 2017 - Elsevier
Since the 1990s and the discovery of the first Single Molecule Magnets (SMMs), chemists
and physicists have been working in concert to elaborate such molecular systems and …