The concept of active site in heterogeneous catalysis
C Vogt, BM Weckhuysen - Nature Reviews Chemistry, 2022 - nature.com
Catalysis is at the core of chemistry and has been essential to make all the goods
surrounding us, including fuels, coatings, plastics and other functional materials. In the near …
surrounding us, including fuels, coatings, plastics and other functional materials. In the near …
Designing sites in heterogeneous catalysis: are we reaching selectivities competitive with those of homogeneous catalysts?
F Zaera - Chemical Reviews, 2022 - ACS Publications
A critical review of different prominent nanotechnologies adapted to catalysis is provided,
with focus on how they contribute to the improvement of selectivity in heterogeneous …
with focus on how they contribute to the improvement of selectivity in heterogeneous …
Small-pore zeolites: synthesis and catalysis
M Dusselier, ME Davis - Chemical reviews, 2018 - ACS Publications
In the past decade or so, small-pore zeolites have received greater attention than large-and
medium-pore molecular sieves that have historically dominated the literature. This is …
medium-pore molecular sieves that have historically dominated the literature. This is …
New trends in tailoring active sites in zeolite-based catalysts
This review addresses the recent developments and trends in tailoring the nature and local
properties of active sites in zeolite-based catalysts, with a special focus on novel extra-large …
properties of active sites in zeolite-based catalysts, with a special focus on novel extra-large …
Dynamic multinuclear sites formed by mobilized copper ions in NOx selective catalytic reduction
Copper ions exchanged into zeolites are active for the selective catalytic reduction (SCR) of
nitrogen oxides (NO x) with ammonia (NH3), but the low-temperature rate dependence on …
nitrogen oxides (NO x) with ammonia (NH3), but the low-temperature rate dependence on …
Methane to methanol: structure–activity relationships for Cu-CHA
DK Pappas, E Borfecchia, M Dyballa… - Journal of the …, 2017 - ACS Publications
Cu-exchanged zeolites possess active sites that are able to cleave the C–H bond of
methane at temperatures≤ 200° C, enabling its selective partial oxidation to methanol …
methane at temperatures≤ 200° C, enabling its selective partial oxidation to methanol …
Structure and Reactivity of Oxygen-Bridged Diamino Dicopper(II) Complexes in Cu-Ion-Exchanged Chabazite Catalyst for NH3-Mediated Selective Catalytic …
The NH3-mediated selective catalytic reduction (NH3-SCR) of NOx over Cu-ion-exchanged
chabazite (Cu-CHA) catalysts is the basis of the technology for abatement of NOx from …
chabazite (Cu-CHA) catalysts is the basis of the technology for abatement of NOx from …
Cu-CHA–a model system for applied selective redox catalysis
E Borfecchia, P Beato, S Svelle, U Olsbye… - Chemical Society …, 2018 - pubs.rsc.org
We review the structural chemistry and reactivity of copper-exchanged molecular sieves with
chabazite (CHA) topology, as an industrially applied catalyst in ammonia mediated …
chabazite (CHA) topology, as an industrially applied catalyst in ammonia mediated …
Recent advances in hybrid metal oxide–zeolite catalysts for low-temperature selective catalytic reduction of NOx by ammonia
A hybrid catalytic system comprised of metal oxide and Cu or Fe exchanged zeolite
components represents a potential advancement of state-of-the-art for selective catalytic …
components represents a potential advancement of state-of-the-art for selective catalytic …
Analysis and control of acid sites in zeolites
A Palčić, V Valtchev - Applied Catalysis A: General, 2020 - Elsevier
The exceptional catalytic performance of zeolites is due to the presence of active sites in a
shape-selective environment, ie, in micropores with molecular dimensions. The present …
shape-selective environment, ie, in micropores with molecular dimensions. The present …