Recent advances in heterogeneous catalytic hydrogenation and dehydrogenation of N-heterocycles

Z Wei, F Shao, J Wang - Chinese Journal of Catalysis, 2019 - Elsevier
The selective hydrogenation of quinolines to 1, 2, 3, 4-tetrahydroquinolines (py-THQ) and its
derivatives has attracted a considerable amount of attention as they show great versatility in …

Amine‐Borane Dehydrogenation and Transfer Hydrogenation Catalyzed by α‐Diimine Cobaltates

TM Maier, S Sandl, IG Shenderovich… - … A European Journal, 2019 - Wiley Online Library
Anionic α‐diimine cobalt complexes, such as [K (thf) 1.5 {(DippBIAN) Co (η4‐cod)}](1; Dipp=
2, 6‐diisopropylphenyl, cod= 1, 5‐cyclooctadiene), catalyze the dehydrogenation of several …

Selective hydroboration of unsaturated bonds by an easily accessible heterotopic cobalt catalyst

C Li, S Song, Y Li, C Xu, Q Luo, Y Guo… - Nature …, 2021 - nature.com
Homogeneous earth-abundant metal catalysis based on well-defined molecular complexes
has achieved great advance in synthetic methodologies. However, sophisticated ligand …

Generalized chemoselective transfer hydrogenation/hydrodeuteration

Y Wang, X Cao, L Zhao, C Pi, J Ji… - Advanced Synthesis & …, 2020 - Wiley Online Library
A generalized, simple and efficient transfer hydrogenation of unsaturated bonds has been
developed using HBPin and various proton reagents as hydrogen sources. The substrates …

Counterion Effect in Cobaltate‐Catalyzed Alkene Hydrogenation

M Gawron, F Gilch, D Schmidhuber… - Angewandte …, 2024 - Wiley Online Library
We show that countercations exert a remarkable influence on the ability of anionic cobaltate
salts to catalyze challenging alkene hydrogenations. An evaluation of the catalytic properties …

Homogeneous vs. heterogeneous: mechanistic insights into iron group metal-catalyzed reductions from poisoning experiments

D Gärtner, S Sandl, AJ von Wangelin - Catalysis Science & Technology, 2020 - pubs.rsc.org
Iron group metal catalysts constitute a promising alternative to well-established noble metal
catalysts in reduction reactions. However, the development of effective 3d metal catalysts …

Effect of BaNH, CaNH, Mg3N2 on the activity of Co in NH3 decomposition catalysis

P Yu, H Wu, J Guo, P Wang, F Chang, W Gao… - Journal of Energy …, 2020 - Elsevier
Abstract Development of active and non-noble metal-based catalyst for H 2 production via
NH 3 decomposition is crucial for the implementation of NH 3 as a H 2 carrier. Co-based …

Synthesis of Bio‐Based Silane Coupling Agents by the Modification of Eugenol

T Sokolnicki, A Franczyk, B Janowski… - … Synthesis & Catalysis, 2021 - Wiley Online Library
A simple method for the synthesis of new bio‐based silane coupling agents (SCAs) with a
terpene aromatic core by the functionalization of cheap, natural eugenol and its sulfur …

Role of benzene tricarboxylic acid in regulating cobalt-titania interface-interaction to access highly dispersed cobalt nanoparticles catalyst

J Chen, X Luo, X Wang, X Yang - Applied Catalysis A: General, 2023 - Elsevier
Finding a robust cobalt catalyst with highly exposed metallic, active sites has been
challenging but highly desirable. Extending our in-situ hybridization route, herein we …

What 27Al NMR spectroscopy can offer to study of multicomponent catalytic hydrogenation systems?

YY Titova, FK Schmidt - Journal of Organometallic Chemistry, 2022 - Elsevier
The multicomponent catalytic systems formed on the basis of LiAlH 4 and, in some case, in
the presence of modifying additives (eg normal or tertiary butyl alcohols) have been studied …