Citric acid as a complexing agent in chemical mechanical polishing slurries for cobalt films for interconnect applications

R Popuri, KV Sagi, SR Alety, BC Peethala… - ECS Journal of Solid …, 2017 - iopscience.iop.org
A colloidal silica-based slurry (3–10 wt%) containing H 2 O 2 (1 wt%) and citric acid (50 mM)
was found to polish chemical vapor-deposited (CVD) cobalt (Co) films with removal rates …

Chemical and mechanical aspects of a Co-Cu planarization scheme based on an alkaline slurry formulation

MC Turk, X Shi, DAJ Gonyer… - ECS Journal of Solid State …, 2015 - iopscience.iop.org
Copper interconnects for the sub-22 nm technology nodes are designed to have diffusion
barriers/liners of significantly reduced thickness and unconventional materials. The …

Chemical mechanical polishing of chemical vapor deposited Co films with minimal corrosion in the Cu/Co/Mn/SiCOH patterned structures

KV Sagi, LG Teugels, MH Van Der Veen… - ECS Journal of Solid …, 2017 - iopscience.iop.org
This work describes the dissolution and corrosion of chemical vapor deposited (CVD) Co
films determined using aqueous mixtures of H 2 O 2, oxalic acid (OA) and nicotinic acid (NA) …

Effect of ethylenediamine on CMP performance of ruthenium in H 2 O 2-based slurries

Y Xu, T Ma, Y Liu, B Tan, S Zhang, Y Wang, G Song - RSC advances, 2022 - pubs.rsc.org
With the aggressive scaling of integrated circuits, ruthenium has been proposed as the next
generation barrier material to replace the conventional bilayer of tantalum and tantalum …

Synergistic effect of 1, 2, 4-triazole and phytic acid as inhibitors on copper film CMP for ruthenium-based copper interconnected and the surface action mechanism …

F Luo, X Niu, H Yan, Y Zhang, M Qu, Y Zhu… - Materials Science in …, 2023 - Elsevier
Ruthenium (Ru) has been selected as the next-generation barrier material for copper (Cu)
interconnects due to its excellent electrical properties, high breakdown voltage, low leakage …

Tribo-electrochemical characterization of Ru, Ta and Cu CMP systems using percarbonate based solutions

X Shi, DE Simpson, D Roy - ECS Journal of Solid State Science …, 2015 - iopscience.iop.org
Defect-control is a critical requirement for chemical mechanical planarization (CMP) of the
ultrathin diffusion barriers considered for the new Cu-interconnects. The challenging task of …

Synergistic effect of glycine and BTA on step height reduction efficiency after copper CMP in weakly alkaline slurry

C Yan, Y Liu, J Zhang, C Wang, W Zhang… - ECS Journal of Solid …, 2016 - iopscience.iop.org
The synergistic and competitive relationship of glycine and benzotriazole (BTA) in a
peroxide-based weakly alkaline slurry during the copper chemical mechanical planarization …

Cleaning solutions for ultrathin Co barriers for advanced technology nodes

SR Alety, URK Lagudu, R Popuri… - ECS Journal of Solid …, 2017 - iopscience.iop.org
Co, a candidate material for barrier and capping layers in 10 nm and smaller Cu
interconnects, is prone to corrosion and galvanic corrosion during chemical mechanical …

Experimental Strategies for Studying Tribo-Electrochemical Aspects of Chemical–Mechanical Planarization

K Gamagedara, D Roy - Lubricants, 2024 - mdpi.com
Chemical–mechanical planarization (CMP) is used to smoothen the topographies of a rough
surface by combining several functions of tribology (friction, lubrication), chemistry, and …

Micro-galvanic corrosion of Cu/Ru couple in potassium periodate (KIO4) solution

J Cheng, J Pan, T Wang, X Lu - Corrosion Science, 2018 - Elsevier
This paper focuses on the study of micro-galvanic corrosion of the Cu/Ru couple in KIO 4
solution. Practical nobility across the Cu/Ru interface was evaluated by Volta potential …