Copper-catalyzed functionalization of 1, 3-dienes: hydrofunctionalization, borofunctionalization, and difunctionalization

GJP Perry, T Jia, DJ Procter - ACS Catalysis, 2019 - ACS Publications
The catalytic conversion of chemical feedstocks into products of medicinal and agricultural
value is a key theme across modern synthetic chemistry. As 1, 3-dienes are readily available …

Hydrodeoxygenation of guaiacol to phenol using endogenous hydrogen induced by chemo-splitting of water over a versatile nano-porous Ni catalyst

X Ren, Z Sun, J Lu, J Cheng, P Zhou, X Yu, Z Rong… - Green …, 2023 - pubs.rsc.org
In this work, an innovative route for upgrading biomass-derived phenolic monomers by
“hydrogen-free” hydrodeoxygenation (HDO) was proposed and evaluated. The HDO …

Photoredox Ni-catalyzed branch-selective reductive coupling of aldehydes with 1, 3-dienes

YL Li, WD Li, ZY Gu, J Chen, JB Xia - ACS Catalysis, 2019 - ACS Publications
We report here a Ni-catalyzed reductive coupling of aldehydes with widely available 1, 3-
dienes under visible-light photoredox dual catalysis. The homoallyic alcohols are obtained …

[HTML][HTML] Recent Advances in Novel Catalytic Hydrodeoxygenation Strategies for Biomass Valorization without Exogenous Hydrogen Donors—A Review

B Zhao, B Du, J Hu, Z Huang, S Xu, Z Chen, D Cheng… - Catalysts, 2024 - mdpi.com
Driven by the growing energy crisis and environmental concerns regarding the utilization of
fossil fuels, biomass liquefaction has emerged as a highly promising technology for the …

Copper‐Catalyzed Highly Selective Protoboration of CF3‐Containing 1,3‐Dienes

J Wu, H Wu, X Li, X Liu, Q Zhao, G Huang… - Angewandte …, 2021 - Wiley Online Library
The copper‐catalyzed highly selective protoboration of CF3‐containing conjugated diene
with proton source and B2Pin2 has been developed. This chemistry could suppress the well …

Recent Advances about Protoboration of Conjugated Dienes

Z Chenchen, N Changhao, L Xinyu… - Chinese Journal of …, 2021 - sioc-journal.cn
The protoboration of conjugated diene is a kind of important strategy for the synthesis of
allylic borides and homo-allylic borides, because of mild reaction conditions and wide …

Copper-Catalyzed Highly Enantioselective 1, 4-Protoboration of Terminal 1, 3-Dienes

Q Guan, Y Ji, Q Zhao, C Zhang - CCS Chemistry, 2022 - chinesechemsoc.org
The copper-catalyzed, highly enantioselective 1, 4-protoboration of terminal 1, 3-dienes with
proton source and B2Pin2 has been developed. Chiral allylic boronate reagents, which are …

Cobalt-Catalyzed Z to E Geometrical Isomerization of 1,3-Dienes

W Wang, S He, Y Zhong, J Chen, C Cai… - The Journal of …, 2022 - ACS Publications
An efficient cobalt-catalyzed geometrical isomerization of 1, 3-dienes is described. In the
combination of a CoCl2 precatalyst with an amido-diphosphine-oxazoline ligand, the …

Cu-Catalyzed highly regioselective 1, 2-hydrocarboxylation of 1, 3-dienes with CO 2

P Zhang, Z Zhou, R Zhang, Q Zhao… - Chemical …, 2020 - pubs.rsc.org
A practical copper-catalyzed highly regioselective 1, 2-hydrocarboxylation of terminal 1, 3-
diene with carbon dioxide has been developed. Under mild reaction conditions, this …

Nickel-catalyzed alkenylboration of alkenylarenes to access homoallylic boronic esters

P Zhang, C Zou, Q Zhao, C Zhang - Organic Chemistry Frontiers, 2021 - pubs.rsc.org
A practical nickel-catalyzed highly selective alkenylboration of alkenylarenes has been
developed. Under mild reaction conditions, a series of structurally interesting homoallylic …