Rise of conjugated poly-ynes and poly (metalla-ynes): from design through synthesis to structure–property relationships and applications

A Haque, RA Al-Balushi, IJ Al-Busaidi, MS Khan… - Chemical …, 2018 - ACS Publications
Conjugated poly-ynes and poly (metalla-ynes) constitute an important class of new materials
with potential application in various domains of science. The key factors responsible for the …

Syntheses, structures and bonding of 3d metal alkynyl complexes of cyclam and its derivatives

SD Banziger, T Ren - Journal of Organometallic Chemistry, 2019 - Elsevier
Described in this review is the chemistry of 3 d metal alkynyls based on tetraaza macrocyclic
ligands. Both the abundance of 3 d metals and easy access to the tetraazacyclotetradecane …

Synthesis and characterizations of macrocyclic Cr (III) and Co (III) 1-ethynyl naphthalene and 9-ethynyl anthracene complexes: An investigation of structural and …

EC Judkins, M Zeller, T Ren - Inorganic Chemistry, 2018 - ACS Publications
Reported herein are the syntheses and structural and emission spectroscopic
characterizations of new CrIII (HMC) and CoIII (cyclam) complexes bearing fluorophore …

Synthesis and Investigation of Macrocyclic CrIII Bis(alkynyl) Complexes: Structural and Spectroscopic Properties

EC Judkins, SF Tyler, M Zeller… - European Journal of …, 2017 - Wiley Online Library
The synthesis and characterization of four new CrIII–bis (alkynyl) complexes bearing the
macrocyclic tetraaza ligand DMC (DMC= 5, 12‐dimethyl‐1, 4, 8, 11 …

Improving redox reversibility and intermetallic coupling of Co (III) alkynyls through tuning of frontier orbitals

BL Mash, Y Yang, T Ren - Organometallics, 2020 - ACS Publications
Reported herein are the syntheses and characterizations for a series of butadiyndiyl-bridged
CoIII (MPC)(MPC= 5, 12-dimethyl-7, 14-diphenyl-1, 4, 8, 11-tetraazacyclotetradecane) …

Co (III) phenylacetylide complexes supported by tetraazamacrocyclic ligands: Syntheses and characterizations

BL Mash, T Ren - Journal of Organometallic Chemistry, 2019 - Elsevier
Reported herein are the syntheses and characterization of mono-and bis-Co (III)
phenylacetylide complexes trans-[Co (L)(C 2 Ph) Cl]+(2a/b) and trans-[Co (L)(C 2 Ph) …

A unique series of chromium (III) mono-alkynyl complexes supported by tetraazamacrocycles

AJ Schuman, SFT Robey, EC Judkins, M Zeller… - Dalton …, 2021 - pubs.rsc.org
Described herein is the synthesis and characterization of macrocyclic CrIII mono-alkynyl
complexes. By using the meso-form of the tetraazamacrocycle HMC (HMC= 5, 5, 7, 12, 12 …

Chromium (III) Bis-alkynyl complexes supported by C-substituted cyclam MPC

AJ Schuman, MM Mills, LR Segura… - Journal of …, 2021 - Elsevier
Macrocyclic Cr III bis-alkynyl complexes have recently been used as a precursor in the
synthesis of mono-alkynyl complexes, which can serve as synthetic intermediates towards …

[PDF][PDF] research communications

J Cˇernák, J Kuchár, M Hegedüs - Acta Cryst, 2017 - researchgate.net
Crystallization from an aqueous methanol system composed of Ni (NO3) 2, 2, 20-bipyridine
(bpy) and LiTCNQ (TCNQ is 7, 7, 8, 8-tetracyanoquinodimethane) in a 1: 3: 2 molar ratio …

[HTML][HTML] Disorder of the dimeric TCNQ–TCNQ unit in the crystal structure of [Ni (bpy) 3] 2 (TCNQ–TCNQ)(TCNQ) 2· 6H2O (TCNQ is 7, 7, 8, 8 …

J Černák, J Kuchár, M Hegedüs - Acta Crystallographica Section E …, 2017 - scripts.iucr.org
Crystallization from an aqueous methanol system composed of Ni (NO3) 2, 2, 2′-bipyridine
(bpy) and LiTCNQ (TCNQ is 7, 7, 8, 8-tetracyanoquinodimethane) in a 1: 3: 2 molar ratio …