Geometry-controlled reactivity and dynamics in organic molecules
It is well established that strain in organic molecules is linked to having nonideal bond
lengths, bond angles and unfavourable non-covalent interactions. The constrained …
lengths, bond angles and unfavourable non-covalent interactions. The constrained …
Molecular Ball Joints: Mechanochemical Perturbation of Bullvalene Hardy–Cope Rearrangements in Polymer Networks
The solution-state fluxional behavior of bullvalene has fascinated physical organic and
supramolecular chemists alike. Little effort, however, has been put into investigating …
supramolecular chemists alike. Little effort, however, has been put into investigating …
Modular, Enantioselective Entry into Polysubstituted Shapeshifting Molecules
A Sanchez, VM Gonzalez, J Sakamoto… - Journal of the …, 2024 - ACS Publications
Dynamic, shapeshifting hydrocarbons have emerged as enabling frameworks across drug
discovery, materials science, and catalysis. Their employment, however, is often hampered …
discovery, materials science, and catalysis. Their employment, however, is often hampered …