Manganese-catalyzed hydrogenation, dehydrogenation, and hydroelementation reactions
The emerging field of organometallic catalysis has shifted towards research on Earth-
abundant transition metals due to their ready availability, economic advantage, and novel …
abundant transition metals due to their ready availability, economic advantage, and novel …
Strategies and mechanisms of metal–ligand cooperativity in first-row transition metal complex catalysts
MR Elsby, RT Baker - Chemical Society Reviews, 2020 - pubs.rsc.org
The use of metal–ligand cooperation (MLC) by transition metal bifunctional catalysts has
emerged at the forefront of homogeneous catalysis science. Specially designed ligands can …
emerged at the forefront of homogeneous catalysis science. Specially designed ligands can …
Reversible hydrogenation of carbon dioxide to formic acid using a Mn-pincer complex in the presence of lysine
D Wei, R Sang, P Sponholz, H Junge, M Beller - Nature Energy, 2022 - nature.com
Efficient hydrogen storage and release are essential for effective use of hydrogen as an
energy carrier. In principle, formic acid could be used as a convenient hydrogen storage …
energy carrier. In principle, formic acid could be used as a convenient hydrogen storage …
Homogeneous catalysis by cobalt and manganese pincer complexes
A Mukherjee, D Milstein - ACS Catalysis, 2018 - ACS Publications
Homogeneous catalysis of organic transformations by metal complexes has been mostly
based on complexes of noble metals. In recent years, tremendous progress has been made …
based on complexes of noble metals. In recent years, tremendous progress has been made …
Catalytic (de) hydrogenation promoted by non-precious metals–Co, Fe and Mn: recent advances in an emerging field
Catalytic hydrogenation and dehydrogenation reactions form the core of the modern
chemical industry. This vast class of reactions is found in any part of chemical synthesis …
chemical industry. This vast class of reactions is found in any part of chemical synthesis …
Homogeneous manganese-catalyzed hydrogenation and dehydrogenation reactions
Y Wang, M Wang, Y Li, Q Liu - Chem, 2021 - cell.com
The development of novel and efficient earth-abundant metal catalysts as inexpensive and
sustainable alternatives to noble-metal catalysts is a rapidly expanding and evolving field of …
sustainable alternatives to noble-metal catalysts is a rapidly expanding and evolving field of …
Manganese complexes for (de) hydrogenation catalysis: a comparison to cobalt and iron catalysts
F Kallmeier, R Kempe - Angewandte Chemie International …, 2018 - Wiley Online Library
The sustainable use of the resources on our planet is essential. Noble metals are very rare
and are diversely used in key technologies, such as catalysis. Manganese is the third most …
and are diversely used in key technologies, such as catalysis. Manganese is the third most …
Computational approach to molecular catalysis by 3d transition metals: challenges and opportunities
Computational chemistry provides a versatile toolbox for studying mechanistic details of
catalytic reactions and holds promise to deliver practical strategies to enable the rational in …
catalytic reactions and holds promise to deliver practical strategies to enable the rational in …
Bis (N‐Heterocyclic Carbene) Manganese (I) Complexes: Efficient and Simple Hydrogenation Catalysts
NF Both, A Spannenberg, H Jiao, K Junge… - Angewandte …, 2023 - Wiley Online Library
The use of bis (NHC) manganese (I) complexes 3 as catalysts for the hydrogenation of
esters was investigated. For that purpose, a series of complexes has been synthesized via …
esters was investigated. For that purpose, a series of complexes has been synthesized via …
The role of the metal-bound N–H functionality in Noyori-type molecular catalysts
PA Dub, JC Gordon - Nature Reviews Chemistry, 2018 - nature.com
Noyori-type catalysts have found numerous applications in research and industrial settings.
The central mechanistic component of such catalysts is a metal centre coordinated to a N–H …
The central mechanistic component of such catalysts is a metal centre coordinated to a N–H …