Chemical transformations that result in either the formation or cleavage of carbon–
heteroatom bonds are among the most important processes in the chemical sciences …

1, 3-N, O-Chelating ligands are ubiquitous in nature owing to their occurrence as α-chiral
amino acids in metalloproteins. These structural units also display diverse coordination …

The selective synthesis of Z-alkenes in alkyne semihydrogenation relies on the reactivity
difference of the catalysts toward the starting materials and the products. Here we report Z …

An air-stable half-sandwich nickel (II) complex bearing a phosphinophenolato ligand, Cp* Ni
(1, 2-Ph2PC6H4O)(1), has been designed and synthesized for activation of HBpin and …

The development of ligands plays a key role and provides important innovations in
homogeneous catalysis. In this context, we report a novel class of ferrocenyl phosphines for …

A half-sandwich molybdenum (II) thiolate complex with a η2-MeCN ligand, Cp* Mo (1, 2-
Ph2PC6H4S)(η2-NCMe)(1 (η2-NCMe)), was found to catalyze transfer hydrogenation of …

The transition-metal-catalyzed nitrenoid transfer reaction is one of the most attractive
methods for installing a new C–N bond into diverse reactive units. While numerous selective …

This paper describes a cooperative iron–thiolate catalyst Cp* Fe (1, 2-Ph2PC6H4S)(NCMe)(
Cp*–= C5Me5–,[1 (NCMe)]) for regioselective hydroboration of aryl epoxide by …

We report an iron system, Cp* Fe (1, 2-R2PC6H4X), which controls the Markovnikov and
anti-Markovnikov hydrostannation of alkynes by tuning the ionic metal–heteroatom bonds …

This review covers the main synthetic routes to and the corresponding mechanisms of
phosphoramidate formation. The synthetic routes can be separated into six categories: salt …