The use of two or more metal catalysts in a reaction is a powerful synthetic strategy to access
complex targets efficiently and selectively from simple starting materials. While capable of …

The generation of azide radical (N3˙) occurs from its precursors primarily via a single
electron transfer (SET) process or homolytic cleavage by chemical methods or advanced …

We describe carbazolyl dicyanobenzene (CDCB)-based donor–acceptor (D–A)
fluorophores as a class of cheap, easily accessible, and efficient metal-free photoredox …

The cross-coupling of sp3-hybridized organoboron reagents via photoredox/nickel dual
catalysis represents a new paradigm of reactivity for engaging alkylmetallic reagents in …

Organosilicon compounds act as a nucleophile upon activation by an appropriate base and
behave in a manner similar to main-group organometallic reagents. In the last decades …

Iodine reagents have been identified as economically and ecologically benign alternatives
to transition metals, although their application as molecular catalysts in challenging C H …

Single-electron transmetalation is recognized as an enabling technology for the mild transfer
of alkyl groups to transition metal catalysts in cross-coupling reactions. Hypercoordinate …

Direct access to complex, enantiopure benzylamine architectures using a synergistic iridium
photoredox/nickel cross‐coupling dual catalysis strategy has been developed. New C …

Despite the significance of sultines in synthesis, medicine, and materials science, the
chemistry of sultines has remained unexplored due to their inaccessibility. Herein, we …

Single-electron transmetalation has emerged as an enabling paradigm for the cross-
coupling of Csp3 hybridized organotrifluoroborates. Cross-coupling of α …