[HTML][HTML] Recent synthetic efforts towards high energy density materials: How to design high-performance energetic structures?
J Zhou, J Zhang, B Wang, L Qiu, R Xu, AB Sheremetev - FirePhysChem, 2022 - Elsevier
Energetic material is a very essential company of compounds, widely used in various fields,
primarily in the military industry and space technologies. These compounds are unique in …
primarily in the military industry and space technologies. These compounds are unique in …
[HTML][HTML] The devil is in the details: The chemical basis and mechanistic versatility of flavoprotein monooxygenases
M Toplak, A Matthews, R Teufel - Archives of Biochemistry and Biophysics, 2021 - Elsevier
The ubiquitous flavoenzymes commonly catalyze redox chemistry such as the
monooxygenation of organic substrates and are both widely utilized in nature (eg, in primary …
monooxygenation of organic substrates and are both widely utilized in nature (eg, in primary …
Photoinduced Site-Selective Functionalization of Aliphatic C–H Bonds by Pyridine N-oxide Based HAT Catalysts
B Wang, C Ascenzi Pettenuzzo, J Singh… - ACS …, 2022 - ACS Publications
Readily available and facilely tunable pyridine N-oxides have been developed as effective
photoinduced hydrogen-atom-transfer (HAT) catalysts for site-selective C–H …
photoinduced hydrogen-atom-transfer (HAT) catalysts for site-selective C–H …
Visible‐Light‐Mediated C‐2 Functionalization and Deoxygenative Strategies in Heterocyclic N‐Oxides
Heterocyclic N‐oxides are prevalent in numerous natural products with broad applications in
pharmaceuticals, agrochemicals, material sciences, and asymmetric synthesis. Owing to …
pharmaceuticals, agrochemicals, material sciences, and asymmetric synthesis. Owing to …
Aminoperoxide adducts expand the catalytic repertoire of flavin monooxygenases
A Matthews, R Saleem-Batcha, JN Sanders… - Nature chemical …, 2020 - nature.com
One of the hallmark reactions catalyzed by flavin-dependent enzymes is the incorporation of
an oxygen atom derived from dioxygen into organic substrates. For many decades, these …
an oxygen atom derived from dioxygen into organic substrates. For many decades, these …
Surface Grafted N‐Oxides have Low‐Fouling and Antibacterial Properties
N Burmeister, E Zorn, A Farooq… - Advanced Materials …, 2023 - Wiley Online Library
Low‐fouling materials are often generated by surface zwitterionization with polymers. In this
context, poly‐N‐oxides have recently attracted considerable attention as biomimetic stealth …
context, poly‐N‐oxides have recently attracted considerable attention as biomimetic stealth …
Selective Hydroxylation of C(sp3)−H Bonds in Steroids
H Abas, P Blencowe, JL Brookfield… - … –A European Journal, 2023 - Wiley Online Library
Steroids are highly prevalent structures in small‐molecule therapeutics, with the level of
oxidation being key to their biological activity and physicochemical properties. These C …
oxidation being key to their biological activity and physicochemical properties. These C …
Photoinduced diverse reactivity of diazo compounds with nitrosoarenes
S Roy, G Kumar, I Chatterjee - Organic Letters, 2021 - ACS Publications
A diverse reactivity of diazo compounds with nitrosoarene in an oxygen-transfer process and
a formal [2+ 2] cycloaddition is reported. Nitosoarene has been exploited as a mild oxygen …
a formal [2+ 2] cycloaddition is reported. Nitosoarene has been exploited as a mild oxygen …
Catalyst-Free N-Deoxygenation by Photoexcitation of Hantzsch Ester
MO Konev, L Cardinale, A Jacobi von Wangelin - Organic letters, 2020 - ACS Publications
A mild and operationally simple protocol for the deoxygenation of a variety of heteroaryl N-
oxides and nitroarenes has been developed. A mixture of substrate and Hantzsch ester is …
oxides and nitroarenes has been developed. A mixture of substrate and Hantzsch ester is …
Recent Strategies in Non-Heme-Type Metal Complex-Catalyzed Site-, Chemo-, and Enantioselective C–H Oxygenations
D Doiuchi, T Uchida - Synthesis, 2021 - thieme-connect.com
C–H bonds are ubiquitous and abundant in organic molecules. If such C–H bonds can be
converted into the desired functional groups in a site-, chemo-, diastereo-, and enantio …
converted into the desired functional groups in a site-, chemo-, diastereo-, and enantio …