Phenalenyl radical: Smallest polycyclic odd alternant hydrocarbon present in the graphene sheet
Phenalenyl, a zigzag-edged odd alternant hydrocarbon unit can be found in the graphene
nanosheet. Hückel molecular orbital calculations indicate the presence of a nonbonding …
nanosheet. Hückel molecular orbital calculations indicate the presence of a nonbonding …
What's new in stable radical chemistry?
RG Hicks - Organic & biomolecular chemistry, 2007 - pubs.rsc.org
Many kinds of radicals are stable enough to isolate, handle, and store without any special
precautions. The diversity in molecular architectures of these stable radicals is sufficiently …
precautions. The diversity in molecular architectures of these stable radicals is sufficiently …
Radical Single-Molecule Junctions
Radicals are unique molecular systems for applications in electronic devices due to their
open-shell electronic structures. Radicals can function as good electrical conductors and …
open-shell electronic structures. Radicals can function as good electrical conductors and …
Polycyclic Hydrocarbons from [4n]Annulenes: Correlation versus Hybridization Forces in the Formation of Diradicaloids
S Moles Quintero, MM Haley… - Angewandte Chemie …, 2022 - Wiley Online Library
The conceptual connections between [4n] Hückel antiaromaticity, disjoint orbitals,
correlation energy, pro‐aromaticity and diradical character for a variety of extended π …
correlation energy, pro‐aromaticity and diradical character for a variety of extended π …
Pancake bonds: π-Stacked dimers of organic and light-atom radicals
KE Preuss - Polyhedron, 2014 - Elsevier
The nature of the chemical bond is fundamental to the modern concept of chemistry. Species
that exhibit unusual interactions provide a valuable challenge to current theoretical models …
that exhibit unusual interactions provide a valuable challenge to current theoretical models …
Electrically conductive covalent organic frameworks: bridging the fields of organic metals and 2D materials
M Souto, DF Perepichka - Journal of Materials Chemistry C, 2021 - pubs.rsc.org
The discovery of organic metals in the 1970s opened the door to the design of electrical
devices based on traditionally inert (insulating) organic materials. More recently …
devices based on traditionally inert (insulating) organic materials. More recently …
Recent progress in open-shell organic conjugated materials and their aggregated states
S Dong, Z Li - Journal of Materials Chemistry C, 2022 - pubs.rsc.org
In the last few decades, open-shell organic materials have attracted great attention from
scientists due to their new chemical and physical properties, as well as their possible …
scientists due to their new chemical and physical properties, as well as their possible …
Hydrogen bond-promoted metallic state in a purely organic single-component conductor under pressure
T Isono, H Kamo, A Ueda, K Takahashi… - Nature …, 2013 - nature.com
Purely organic materials are generally insulating. Some charge-carrier generation, however,
can provide them with electrical conductivity. In multi-component organic systems, carrier …
can provide them with electrical conductivity. In multi-component organic systems, carrier …
Cethrene: a helically chiral biradicaloid isomer of heptazethrene
We report the synthesis and properties of “cethrene”, the only helically chiral isomer of
heptazethrene with a biradicaloid singlet ground state. Cethrene gives a well‐resolved EPR …
heptazethrene with a biradicaloid singlet ground state. Cethrene gives a well‐resolved EPR …
Recent advances in organic radicals and their magnetism
The review presents an overview of the organic radicals that have been designed and
synthesized recently, and their magnetic properties are discussed. The π-conjugated …
synthesized recently, and their magnetic properties are discussed. The π-conjugated …