Elemental sulfur has been known since Antiquity and found widespread applications in the
preparation of black gunpowder, the synthesis of sulfuric acid as well as other sulfur …

3 H-1, 2-Dithiole-3-thiones are among the best studied classes of polysulfur-containing
heterocycles due to the almost explosive recent interest in these compounds as sources of …

1, 2, 3-Thiadiazoles serve as masked S-electrophilic thia-1, 3-dipoles. Under
rhodium/racemic BINAP catalysis, they undergo denitrogenative (3+ 2) umpolung …

A highly efficient method is disclosed for the synthesis of 1, 2-dichalcogen heterocycles via
[3+ 2] cycloaddition of cyclopropenone derivatives and elemental chalcogens. Different from …

A metal-and oxidant-free photoinduced strategy for thioxo sulfur-selective
trifluoromethylation of β-ketodithioesters at room temperature is reported. Excellent Z/E …

The synthesis of 3, 4-dihydro-2 H-1, 3-thiazines from α-enolic dithioesters and 1, 3, 5-
triazinanes has been achieved via a formal (3+ 3) annulation reaction under thermal …

A simple and practical strategy for the preparation of 1, 2‐dithiole‐3‐thiones via copper‐
catalyzed defluorinative thioannulation of trifluoropropynes has been developed using …

An efficient chemoselective practical route to fully substituted thiazoles and 2, 3-
dihydrothiazoles has been devised by [4+ 1] heterocyclization of α-(N-hydroxy/aryl) imino-β …

Copper-catalyzed aerobic oxidative sulfuration and annulation of propargylamines with
elemental sulfur is described. The tandem reaction involves C–N bond cleavage and the …

Magnesium catalysis proved to be efficient towards [3+ 3] chemo-and diastereoselective
heteroannulation employing racemic Morita–Baylis–Hillman (MBH) acetate as the C3 unit …