Conspectus Carbon monoxide, CO, is one of the most important ligands in organometallic
chemistry. It is an excellent π-acceptor and a moderate σ-donor. Therefore, most of the …

There has been a rapid development in the study of metal carbonyl cations, which exhibit
distinguishing characteristics in comparison with typical metal carbonyl complexes. This …

[Ag (Et2-Bimy) 2][AgBr2](1; Et2-Bimy= diethylbenzimidazol-2-ylidene) was obtained readily
from the reaction of [Et2-BimyH] Br with Ag2O. Compound 2,[Ag (Et2-Bimy) 2] PF6, was …

The review is a summary and analysis of the data characterizing CO adsorption on surface
cationic sites of oxides including supported materials and microporous and mesoporous …

Purified LiAlH4 reacts with fluorinated alcohols HORF to give LiAl (ORF) 4 (RF=− CH (CF3)
2, 2 a;− C (CH3)(CF3) 2, 2 b;− C (CF3) 3, 2 c) in 77 to 90% yield. The crude lithium …

Gold-carbene complexes appear to be quite stable and have been widely studied. 1-26
Although the other transition group I metals, copper and silver, have very common usage as …

In this Communication, the substituent labels for P-heterocyclic carbodiphosphoranes 2
(Scheme 2) were incorrectly shown and incorrectly listed in Table 1 for the proton affinities …

We provide the first observation and characterization of super electrophilic metal cations on
a solid support. For Pd/SSZ-13, the results of our combined experimental (Fourier transform …

MP2 calculations show that the D∞ h isoelectronic dicarbonyl complexes [M (CO) 2] n (Mn=
Rh−, Pd0, Cu+, Ag+, Au+, Zn2+, Cd2+, Hg2+) depicted in structure 1 can be classified as …

Thesynthesis and characterization of salts of the cationic silver (I) carbonylcomplexes [Ag
(CO)]+ and [Ag (CO) 2]+ are reported. The counterions used include OTeF5* and the weakly …