Understanding the electric double-layer structure, capacitance, and charging dynamics

J Wu - Chemical Reviews, 2022 - ACS Publications
Significant progress has been made in recent years in theoretical modeling of the electric
double layer (EDL), a key concept in electrochemistry important for energy storage …

Electrochemical methods for water purification, ion separations, and energy conversion

MA Alkhadra, X Su, ME Suss, H Tian, EN Guyes… - Chemical …, 2022 - ACS Publications
Agricultural development, extensive industrialization, and rapid growth of the global
population have inadvertently been accompanied by environmental pollution. Water …

Fluids and electrolytes under confinement in single-digit nanopores

NR Aluru, F Aydin, MZ Bazant, D Blankschtein… - Chemical …, 2023 - ACS Publications
Confined fluids and electrolyte solutions in nanopores exhibit rich and surprising physics
and chemistry that impact the mass transport and energy efficiency in many important …

Interfacial layering in the electric double layer of ionic liquids

JP de Souza, ZAH Goodwin, M McEldrew… - Physical Review Letters, 2020 - APS
Ions in ionic liquids and concentrated electrolytes reside in a crowded, strongly interacting
environment, leading to the formation of discrete layers of charges at interfaces and spin …

Tuning Ionic Screening To Accelerate Electrochemical CO2 Reduction in Ionic Liquid Electrolytes

B Liu, W Guo, MA Gebbie - ACS Catalysis, 2022 - ACS Publications
Electric double layer formation often governs the rate and selectivity of CO2 electrochemical
reduction. Ionic correlations critically define double layer properties that are essential to …

Molecular mean-field theory of ionic solutions: A Poisson-Nernst-Planck-Bikerman model

JL Liu, B Eisenberg - Entropy, 2020 - mdpi.com
We have developed a molecular mean-field theory—fourth-order Poisson–Nernst–Planck–
Bikerman theory—for modeling ionic and water flows in biological ion channels by treating …

Modified Poisson–Boltzmann equations and macroscopic forces in inhomogeneous ionic fluids

YA Budkov, AL Kolesnikov - Journal of Statistical Mechanics …, 2022 - iopscience.iop.org
We propose a field-theoretical approach based on the thermodynamic perturbation theory
and within it derive a grand thermodynamic potential of the inhomogeneous ionic fluid as a …

Noether's second theorem and covariant field theory of mechanical stresses in inhomogeneous ionic liquids

PE Brandyshev, YA Budkov - The Journal of chemical physics, 2023 - pubs.aip.org
In this paper, we present a covariant approach that utilizes Noether's second theorem to
derive a symmetric stress tensor from the grand thermodynamic potential functional. We …

Theory of surface forces in multivalent electrolytes

RP Misra, JP de Souza, D Blankschtein, MZ Bazant - Langmuir, 2019 - ACS Publications
Aqueous electrolyte solutions containing multivalent ions exhibit various intriguing
properties, including attraction between like-charged colloidal particles, which results from …

Electric double layer theory for room temperature ionic liquids on charged electrodes: Milestones and prospects

YA Budkov, AL Kolesnikov - Current Opinion in Electrochemistry, 2022 - Elsevier
In this review, we shortly summarize the basic theoretical milestones achieved in the mean-
field theory of room temperature ionic liquids on charged electrodes since the publication of …