Understanding the electric double-layer structure, capacitance, and charging dynamics
J Wu - Chemical Reviews, 2022 - ACS Publications
Significant progress has been made in recent years in theoretical modeling of the electric
double layer (EDL), a key concept in electrochemistry important for energy storage …
double layer (EDL), a key concept in electrochemistry important for energy storage …
Electrochemical methods for water purification, ion separations, and energy conversion
Agricultural development, extensive industrialization, and rapid growth of the global
population have inadvertently been accompanied by environmental pollution. Water …
population have inadvertently been accompanied by environmental pollution. Water …
Fluids and electrolytes under confinement in single-digit nanopores
Confined fluids and electrolyte solutions in nanopores exhibit rich and surprising physics
and chemistry that impact the mass transport and energy efficiency in many important …
and chemistry that impact the mass transport and energy efficiency in many important …
Interfacial layering in the electric double layer of ionic liquids
Ions in ionic liquids and concentrated electrolytes reside in a crowded, strongly interacting
environment, leading to the formation of discrete layers of charges at interfaces and spin …
environment, leading to the formation of discrete layers of charges at interfaces and spin …
Tuning Ionic Screening To Accelerate Electrochemical CO2 Reduction in Ionic Liquid Electrolytes
Electric double layer formation often governs the rate and selectivity of CO2 electrochemical
reduction. Ionic correlations critically define double layer properties that are essential to …
reduction. Ionic correlations critically define double layer properties that are essential to …
Molecular mean-field theory of ionic solutions: A Poisson-Nernst-Planck-Bikerman model
JL Liu, B Eisenberg - Entropy, 2020 - mdpi.com
We have developed a molecular mean-field theory—fourth-order Poisson–Nernst–Planck–
Bikerman theory—for modeling ionic and water flows in biological ion channels by treating …
Bikerman theory—for modeling ionic and water flows in biological ion channels by treating …
Modified Poisson–Boltzmann equations and macroscopic forces in inhomogeneous ionic fluids
YA Budkov, AL Kolesnikov - Journal of Statistical Mechanics …, 2022 - iopscience.iop.org
We propose a field-theoretical approach based on the thermodynamic perturbation theory
and within it derive a grand thermodynamic potential of the inhomogeneous ionic fluid as a …
and within it derive a grand thermodynamic potential of the inhomogeneous ionic fluid as a …
Noether's second theorem and covariant field theory of mechanical stresses in inhomogeneous ionic liquids
PE Brandyshev, YA Budkov - The Journal of chemical physics, 2023 - pubs.aip.org
In this paper, we present a covariant approach that utilizes Noether's second theorem to
derive a symmetric stress tensor from the grand thermodynamic potential functional. We …
derive a symmetric stress tensor from the grand thermodynamic potential functional. We …
Theory of surface forces in multivalent electrolytes
Aqueous electrolyte solutions containing multivalent ions exhibit various intriguing
properties, including attraction between like-charged colloidal particles, which results from …
properties, including attraction between like-charged colloidal particles, which results from …
Electric double layer theory for room temperature ionic liquids on charged electrodes: Milestones and prospects
YA Budkov, AL Kolesnikov - Current Opinion in Electrochemistry, 2022 - Elsevier
In this review, we shortly summarize the basic theoretical milestones achieved in the mean-
field theory of room temperature ionic liquids on charged electrodes since the publication of …
field theory of room temperature ionic liquids on charged electrodes since the publication of …