[HTML][HTML] Recent developments in one-pot stepwise synthesis (OPSS) of small molecules

X Ma, W Zhang - Iscience, 2022 - cell.com
One-pot synthesis is an active topic in organic chemistry due to its intrinsic advantages of
simple operation, high mass efficiency, low cost, and less amount of waste disposal. Among …

Thiosulfonates as emerging reactants: synthesis and applications

P Mampuys, CR McElroy, JH Clark… - Advanced Synthesis …, 2020 - Wiley Online Library
The synthetic strategies towards thiosulfonates (RSO2SR1) are comprehensively reviewed
from their original discovery to recent advances. Incorporation of the green credentials of the …

Copper-decorated covalent organic framework as a heterogeneous photocatalyst for phosphorylation of terminal alkynes

YX Chen, M Zhang, SZ Zhang, ZQ Hao, ZH Zhang - Green Chemistry, 2022 - pubs.rsc.org
A layered covalent organic framework (COF) material based on an imine-linkage with high
thermal and chemical stability was prepared using a deep eutectic solvent (DES) as the …

ppm Pd‐Containing Nanoparticles as Catalysts for Negishi Couplings … in Water

Y Hu, MJ Wong, BH Lipshutz - … Chemie International Edition, 2022 - Wiley Online Library
New technology is reported that enables Negishi couplings to be run under sustainable, far
greener conditions. Thus, ppm Pd‐containing nanoparticles (NPs) have been developed …

Why we might be misusing process mass intensity (PMI) and a methodology to apply it effectively as a discovery level metric

ER Monteith, P Mampuys, L Summerton, JH Clark… - Green …, 2020 - pubs.rsc.org
Process mass intensity (PMI) is a key mass-based metric to evaluate the green credentials of
an individual or sequence of reactions during process and chemical development. The …

Thiosulfonylation of unactivated alkenes with visible-light organic photocatalysis

K Gadde, P Mampuys, A Guidetti, HYV Ching… - Acs …, 2020 - ACS Publications
A metal-free method for the vicinal thiosulfonylation of unactivated alkenes with
thiosulfonates using 9-mesityl-10-methylacridinium perchlorate as the photo-organocatalyst …

Water mediated TBAB catalyzed synthesis of spiro-indoline-pyrano [3, 2-c] quinolines as α-amylase inhibitor and in silico studies

DB Upadhyay, RM Vala, SG Patel, PJ Patel… - Journal of Molecular …, 2023 - Elsevier
Herein, an efficient synthesis of spiro-indoline-pyrano [3, 2-c] quinolines derivatives of
spiroxindolines by the water-mediated three-component condensation reaction of 2 …

Disproportionate Coupling Reaction of Sodium Sulfinates Mediated by BF3·OEt2: An Approach to Symmetrical/Unsymmetrical Thiosulfonates

L Cao, SH Luo, K Jiang, ZF Hao, BW Wang… - Organic …, 2018 - ACS Publications
The BF3· OEt2-mediated disproportionate coupling reaction of sodium sulfinates was found
for the first time. In this reaction, various S–S (O) 2 bonds can be formed, efficiently giving …

Selective C (aryl)–O bond cleavage in biorenewable phenolics

G De Smet, X Bai, BUW Maes - Chemical Society Reviews, 2024 - pubs.rsc.org
Biorefining of lignocellulosic biomass via a lignin first approach delivers a range of products
with high oxygen content. Besides pulp, a lignin oil rich in guaiacols and syringols is …

[HTML][HTML] A more sustainable and highly practicable synthesis of aliphatic isocyanides

KA Waibel, R Nickisch, N Möhl, R Seim, MAR Meier - Green chemistry, 2020 - pubs.rsc.org
Synthesis protocols to convert N-formamides into isocyanides using three different
dehydration reagents (ie p-toluenesulfonyl chloride (p-TsCl), phosphoryl trichloride (POCl3) …