Thiosulfonates as emerging reactants: synthesis and applications

P Mampuys, CR McElroy, JH Clark… - Advanced Synthesis …, 2020 - Wiley Online Library
The synthetic strategies towards thiosulfonates (RSO2SR1) are comprehensively reviewed
from their original discovery to recent advances. Incorporation of the green credentials of the …

C3‐Functionalization of Imidazo[1,2‐a]pyridines

Z Tashrifi… - European Journal of …, 2020 - Wiley Online Library
Among nitrogen‐containing organic compounds, imidazo [1, 2‐a] pyridines, and especially
C3‐functionalized imidazo [1, 2‐a] pyridines, have a wide range of industrial applications in …

Metal-free thiocyanation of imidazoheterocycles through visible light photoredox catalysis

S Mitra, M Ghosh, S Mishra, A Hajra - The Journal of organic …, 2015 - ACS Publications
A visible light mediated, metal-free process for the thiocyanation of imidazoheterocycles has
been developed using eosin Y as a photoredox catalyst under ambient air at room …

Regioselective, Solvent‐ and Metal‐Free Chalcogenation of Imidazo[1,2‐a]pyridines by Employing I2/DMSO as the Catalytic Oxidation System

J Rafique, S Saba, AR Rosario… - Chemistry–A European …, 2016 - Wiley Online Library
Highly efficient molecular‐iodine‐catalyzed chalcogenations (S and Se) of imidazo [1, 2‐a]
pyridines were achieved by using diorganoyl dichalcogenides under solvent‐free …

Iodine-mediated difunctionalization of imidazopyridines with sodium sulfinates: synthesis of sulfones and sulfides

YJ Guo, S Lu, LL Tian, EL Huang, XQ Hao… - The Journal of …, 2018 - ACS Publications
Novel iodine-induced sulfonylation and sulfenylation of imidazopyridines have been
described using sodium sulfinates as the sulfur source. This strategy enables highly …

Visible light-induced C–H sulfenylation using sulfinic acids

P Sun, D Yang, W Wei, M Jiang, Z Wang, L Zhang… - Green …, 2017 - pubs.rsc.org
The visible light and Eosin B-catalyzed direct sulfenylation of sp2 C–H bonds with sulfinic
acids through a photoredox process has been demonstrated at room temperature under …

Visible-light-induced regioselective sulfenylation of imidazopyridines with thiols under transition metal-free conditions

R Rahaman, S Das, P Barman - Green Chemistry, 2018 - pubs.rsc.org
A metal-free visible-light-promoted regioselective C-3 sulfenylation of imidazo [1, 2-a]
pyridines and indoles using thiols has been developed via C (sp2)–H functionalization. This …

Ammonium iodide induced nonradical regioselective sulfenylation of flavones via a C–H functionalization process

W Zhao, P Xie, Z Bian, A Zhou, H Ge… - The Journal of …, 2015 - ACS Publications
A novel and highly regioselective ammonium iodide-induced nonradical sulfenylation
method for the construction of a C–S bond was developed via C–H functionalization. With …

Dual role of p-tosylchloride: copper-catalyzed sulfenylation and metal free methylthiolation of imidazo [1, 2-a] pyridines

C Ravi, DC Mohan, S Adimurthy - Organic & Biomolecular Chemistry, 2016 - pubs.rsc.org
Copper-catalyzed regioselective C-3 sulfenylation of imidazo [1, 2-a] pyridines using p-
tosylchloride as a benign source of sulfenylating agents has been developed. On the other …

Palladium-catalyzed oxidative sulfenylation of indoles and related electron-rich heteroarenes with aryl boronic acids and elemental sulfur

J Li, C Li, S Yang, Y An, W Wu… - The Journal of Organic …, 2016 - ACS Publications
An efficient and convenient palladium-catalyzed C–H bond oxidative sulfenylation of indoles
and related electron-rich heteroarenes with aryl boronic acids and elemental sulfur has …