Ultrafast elementary photochemical processes of organic molecules in liquid solution

T Kumpulainen, B Lang, A Rosspeintner… - Chemical …, 2017 - ACS Publications
Ultrafast photochemical reactions in liquids occur on similar or shorter time scales compared
to the equilibration of the optically populated excited state. This equilibration involves the …

Artificial molecular rotors

GS Kottas, LI Clarke, D Horinek, J Michl - Chemical Reviews, 2005 - ACS Publications
To many, periodic mechanical conformational motion of molecules is mesmerizing to a
degree that is difficult to explain rationally: It is almost as hard to stop watching an image of …

[HTML][HTML] Molecular polaritons for controlling chemistry with quantum optics

F Herrera, J Owrutsky - The Journal of chemical physics, 2020 - pubs.aip.org
This is a tutorial-style introduction to the field of molecular polaritons. We describe the basic
physical principles and consequences of strong light–matter coupling common to molecular …

Structure and dynamics of monohydroxy alcohols—Milestones towards their microscopic understanding, 100 years after Debye

R Böhmer, C Gainaru, R Richert - Physics Reports, 2014 - Elsevier
In 1913 Debye devised a relaxation model for application to the dielectric properties of water
and alcohols. These hydrogen-bonded liquids continue to be studied extensively because …

Heterogeneous dynamics in liquids: fluctuations in space and time

R Richert - Journal of Physics: Condensed Matter, 2002 - iopscience.iop.org
The disordered nature of glass-forming melts gives rise to non-Arrhenius and non-
exponential behaviour of their dynamics. With respect to the microscopic details involved in …

Ultrafast chemistry: Using time-resolved vibrational spectroscopy for interrogation of structural dynamics

ETJ Nibbering, H Fidder, E Pines - Annu. Rev. Phys. Chem., 2005 - annualreviews.org
▪ Abstract Time-resolved infrared (IR) and Raman spectroscopy elucidates molecular
structure evolution during ultrafast chemical reactions. Following vibrational marker modes …

Solvation and rotational dynamics of coumarin 153 in ionic liquids: Comparisons to conventional solvents

H Jin, GA Baker, S Arzhantsev, J Dong… - The journal of …, 2007 - ACS Publications
Steady-state and time-resolved emission spectroscopy with 25 ps resolution are used to
measure equilibrium and dynamic aspects of the solvation of coumarin 153 (C153) in a …

Intermolecular dynamics, interactions, and solvation in ionic liquids

EW Castner Jr, JF Wishart… - Accounts of chemical …, 2007 - ACS Publications
Ionic liquids can simultaneously assume multiple solvent roles, because they are strongly
polar and polarizable solvents and binary solutions and frequently contain very hydrophobic …

Water immobilization at surfactant interfaces in reverse micelles

RE Riter, DM Willard, NE Levinger - The Journal of Physical …, 1998 - ACS Publications
The mobility of water in water/Aerosol OT (AOT)/isooctane reverse micelles has been
investigated via polar solvation dynamics measurements using ultrafast, time-resolved …

Redox reactions of heme-containing metalloproteins: dynamic effects of self-assembled monolayers on thermodynamics and kinetics of cytochrome c electron-transfer …

M Fedurco - Coordination Chemistry Reviews, 2000 - Elsevier
The ability of metalloproteins to recognize their biological redox partners, as well as kinetics
of inter-protein electron-transfer reactions may be affected by chemical modification of amino …