The phenomenon of single-molecule magnetism was established in the early 1990s with the
cluster [Mn 12 O 12 (AcO) 16 (H 2 O) 4]. Since then, a large number of compounds …

Novel functional molecular-based magnetic materials, especially some members of the
Prussian blue family, have gained significant attention over the past few decades as they …

Tailoring the specific magnetic properties of any material relies on the topological control of
the constituent metal ion building blocks. Although this general approach does not seem to …

In 1967 Pederson reported the synthesis of macrocyclic crown ethers and their ability to
selectively bind alkali and alkaline earth ions, 1, 2 and since then supramolecular …

Slow relaxation of the magnetization (ie,“magnet-like” behavior) in materials composed of
magnetically isolated chains was observed for the first time in 2001. This type of behavior …

The design and preparation of stable cyanide-bearing six-coordinate complexes of formula
[MIII (L)(CN) x](x+ l− m)−(M= trivalent transition metal ion and L= polydentate blocking …

A series of cyanide bridged Fe− Co molecular squares,[Co2Fe2 (CN) 6 (tp*) 2 (dtbbpy)
4](PF6) 2· 2MeOH (1),[Co2Fe2 (CN) 6 (tp*) 2 (bpy) 4](PF6) 2· 2MeOH (2), and [Co2Fe2 (CN) …

A unique purely lanthanide-based single-molecule magnet (SMM) with an oxalate bridge
has been designed through a rational synthetic approach. This strategy opens up new …

For single-molecule magnet (SMM) behavior, molecular clusters require Ising
magnetoanisotropy (Dmol< 0) and a large ground-state spin multiplicity.[1] These …

Octacyanometallate-Based Single-Molecule Magnets: CoII9MV6 (M = W, Mo) | Journal of the
American Chemical Society ACS ACS Publications C&EN CAS Find my institution Log In Journal …