Metal-free hydrides are of increasing research interest due to their roles in recent scientific
advances in catalysis, such as hydrogen activation with frustrated Lewis pairs and …

In this work, the thermodynamic and kinetic forces of three NADH analogues as BNAH,
HEH2, and AcrH2, to release hydride ion or hydrogen atom in acetonitrile in chemical …

The reactivity of a nonheme iron (IV)-oxo complex,[(N4Py) FeIV (O)] 2+(N4Py= N, N-bis (2-
pyridylmethyl)-N-bis (2-pyridyl) methylamine), was markedly enhanced by perchloric acid …

The H-donating activity of phenol and the H-abstraction activity of phenol radicals have been
extensively studied. In this article, the second-order rate constants of 25 hydrogen atom …

The object of this fundamental research would reveal the actual antioxidant ability of the
antioxidants using thermo‐kinetic parameter ΔG≠ o which was proposed according to Zhu …

Hydride transfer from dihydronicotinamide adenine dinucleotide (NADH) analogues, such
as 10-methyl-9, 10-dihydroacridine (AcrH2) and its derivatives, 1-benzyl-1, 4 …

Selective two-electron plus two-proton (2e–/2H+) reduction of O2 to hydrogen peroxide by
ferrocene (Fc) or 1, 1′-dimethylferrocene (Me2Fc) in the presence of perchloric acid is …

A classical but new kinetic equation to estimate activation energies of various hydride
transfer reactions was developed according to transition state theory using the Morse-type …

The catalytic hydrogenation of carbon dioxide holds immense promise for applications in
sustainable fuel synthesis and hydrogen storage. Mechanistic studies that connect …

It has recently frequently been found that the kinetic isotope effect (KIE) is independent of
temperature (T) in H-tunneling reactions in enzymes but becomes dependent on T in their …