Near-edge X-ray absorption fine structure spectroscopy in studies of self-assembled monomolecular films

M Zharnikov - Journal of Electron Spectroscopy and Related …, 2023 - Elsevier
This article reviews the application of near-edge X-ray absorption fine structure (NEXAFS)
spectroscopy to characterization of self-assembled monolayers (SAMs) which are an …

Femtosecond charge transfer dynamics in monomolecular films in the context of molecular electronics

M Zharnikov - Accounts of Chemical Research, 2020 - ACS Publications
Conspectus A key issue of molecular electronics (ME) is the correlation between the
molecular structure and the charge transport properties of the molecular framework …

Thiolate versus Selenolate: Structure, Stability, and Charge Transfer Properties

J Ossowski, T Wächter, L Silies, M Kind… - ACS …, 2015 - ACS Publications
Selenolate is considered as an alternative to thiolate to serve as a headgroup mediating the
formation of self-assembled monolayers (SAMs) on coinage metal substrates. There are …

Importance of the Anchor Group Position (Para versus Meta) in Tetraphenylmethane Tripods: Synthesis and Self‐Assembly Features

M Lindner, M Valášek, J Homberg… - … A European Journal, 2016 - Wiley Online Library
The efficient synthesis of tripodal platforms based on tetraphenylmethane with three acetyl‐
protected thiol groups in either meta or para positions relative to the central sp3 carbon for …

Cyano-substituted triptycene-based monolayers on Au (111): Tripodal adsorption, dipole engineering, and charge transfer

S Das, A Asyuda, Y Shoji, A Kosaka… - The Journal of …, 2021 - ACS Publications
Molecules with tripodal anchoring groups are generally capable of forming self-assembled
monolayers (SAMs), which, however, frequently suffer from inhomogeneous bonding …

Orbital-dependent charge transfer dynamics in conjugated self-assembled monolayers

H Hamoudi, S Neppl, P Kao, B Schüpbach, P Feulner… - Physical Review Letters, 2011 - APS
Femtosecond charge transfer (CT) dynamics in a series of self-assembled monolayers with
an oligo (phenylenethynylene) and oligo (phenyl) backbone is addressed by resonant …

Odd–even effects in aryl-substituted alkanethiolate SAMs: nonsymmetrical attachment of aryl unit and its impact on the SAM structure

W Azzam, A Subaihi, M Rohwerder, A Bashir… - Physical Chemistry …, 2024 - pubs.rsc.org
Aryl-substituted alkanethiolate (AT) self-assembled monolayers (SAMs) exhibit typically so-
called odd–even effects, viz. systematic variations in the film structure, packing density, and …

Electron transfer dynamics and structural effects in benzonitrile monolayers with tuned dipole moments by differently positioned fluorine atoms

P Werner, T Wächter, A Asyuda… - … applied materials & …, 2020 - ACS Publications
To understand the influence of the molecular dipole moment on the electron transfer (ET)
dynamics across the molecular framework, two series of differently fluorinated, benzonitrile …

Dipole-induced effects on charge transfer and charge transport. Why do molecular electrets matter?

JB Derr, J Tamayo, EM Espinoza… - Canadian Journal of …, 2018 - cdnsciencepub.com
Charge transfer (CT) and charge transport (CTr) are at the core of life-sustaining biological
processes and of processes that govern the performance of electronic and energy …

Probing charge transfer dynamics in self-assembled monolayers by core hole clock approach

M Zharnikov - Journal of Electron Spectroscopy and Related …, 2015 - Elsevier
This article reviews recent progress in the application of core hole clock approach in the
framework of resonant Auger electron spectroscopy to the monomolecular assembles of …