Femtosecond charge transfer dynamics in monomolecular films in the context of molecular electronics

M Zharnikov - Accounts of Chemical Research, 2020 - ACS Publications
Conspectus A key issue of molecular electronics (ME) is the correlation between the
molecular structure and the charge transport properties of the molecular framework …

The Effects of Embedded Dipoles in Aromatic Self‐Assembled Monolayers

T Abu‐Husein, S Schuster, DA Egger… - Advanced Functional …, 2015 - Wiley Online Library
Using a representative model system, here electronic and structural properties of aromatic
self‐assembled monolayers (SAMs) are described that contain an embedded, dipolar group …

Probing charge transfer dynamics in self-assembled monolayers by core hole clock approach

M Zharnikov - Journal of Electron Spectroscopy and Related …, 2015 - Elsevier
This article reviews recent progress in the application of core hole clock approach in the
framework of resonant Auger electron spectroscopy to the monomolecular assembles of …

Thiolate versus Selenolate: Structure, Stability, and Charge Transfer Properties

J Ossowski, T Wächter, L Silies, M Kind… - ACS …, 2015 - ACS Publications
Selenolate is considered as an alternative to thiolate to serve as a headgroup mediating the
formation of self-assembled monolayers (SAMs) on coinage metal substrates. There are …

Electronic couplings for charge transfer across molecule/metal and molecule/semiconductor interfaces: Performance of the projector operator-based diabatization …

Z Futera, J Blumberger - The Journal of Physical Chemistry C, 2017 - ACS Publications
One principal parameter determining charge transfer rates between molecules and metals is
the electronic coupling strength between the discrete electronic states of the molecule and …

Orbital-dependent charge transfer dynamics in conjugated self-assembled monolayers

H Hamoudi, S Neppl, P Kao, B Schüpbach, P Feulner… - Physical Review Letters, 2011 - APS
Femtosecond charge transfer (CT) dynamics in a series of self-assembled monolayers with
an oligo (phenylenethynylene) and oligo (phenyl) backbone is addressed by resonant …

Synthesis of molecular tripods based on a rigid 9, 9′-spirobifluorene scaffold

M Valasek, K Edelmann, L Gerhard… - The Journal of …, 2014 - ACS Publications
The efficient synthesis of a new tripodal platform based on a rigid 9, 9′-spirobifluorene with
three acetyl protected thiol groups in the positions 2, 3′ and 6′ for deposition on Au (111) …

Electron transfer dynamics and structural effects in benzonitrile monolayers with tuned dipole moments by differently positioned fluorine atoms

P Werner, T Wächter, A Asyuda… - … applied materials & …, 2020 - ACS Publications
To understand the influence of the molecular dipole moment on the electron transfer (ET)
dynamics across the molecular framework, two series of differently fluorinated, benzonitrile …

Spontaneous desorption and phase transitions of self-assembled alkanethiol and alicyclic thiol monolayers chemisorbed on Au (1 1 1) in ultrahigh vacuum at room …

E Ito, H Kang, D Lee, JB Park, M Hara, J Noh - Journal of colloid and …, 2013 - Elsevier
Scanning tunneling microscopy (STM) and X-ray photoelectron spectroscopy (XPS) were
used to examine the surface structure and adsorption conditions of hexanethiol (HT) and …

Reduction of leakage current in amorphous Oxide-Semiconductor Top-gated thin film transistors by interface engineering with dipolar Self-Assembled monolayers

YH Liang, S Kumaran, M Zharnikov, Y Tai - Applied Surface Science, 2021 - Elsevier
Top gate (TG) thin film transistors (TFTs) featuring amorphous metal oxide semiconductors
(a-MOS), such as indium-gallium-zinc-oxide (IGZO), bear a great potential for large-area …