The emerging field of organometallic catalysis has shifted towards research on Earth-
abundant transition metals due to their ready availability, economic advantage, and novel …

Methylation is a well‐known structural modification in organic and medicinal chemistry. This
review summarizes recent advances in methylation by categorizing specific methylation …

N-methylamine functionalities are valuable motifs, which play vital roles in the properties
and activities of essential fine and bulk chemicals including molecules used in life science …

An iron (0) complex bearing a cyclopentadienone ligand catalyzed N-methylation and N-
ethylation of aryl and aliphatic amines with methanol or ethanol in mild and basic conditions …

Methanol can be employed as a green and sustainable methylating agent to form C–C and
C–N bonds via borrowing hydrogen (BH) methodology. Herein we explored the activity of …

An example of homogeneous Mo-catalyzed direct N-alkylation of anilines or nitroarenes with
alcohols is presented. The DFT aimed design suggested the easily accessible bis-NHC-Mo …

Herein, we report commercially available carbon-supported-palladium (Pd/C)-catalyzed N-
methylation of nitroarenes and amines using MeOH as both a C1 and a H2 source. This …

Quinoline-based metal complexes have gained considerable attention in recent years due
to their applications in various fields, including catalysis, material sciences, and medicinal …

Methanol is a potential hydrogen source and C1 synthon, which finds interesting
applications in both chemical synthesis and energy technologies. The effective utilization of …

Herein, control transfer hydrogenation (TH) of azoarenes to hydrazo compounds is
established employing easy-to-synthesize reusable cobalt catalyst using lower amounts of …