Direct photocatalyzed hydrogen atom transfer (d-HAT) can be considered a method of
choice for the elaboration of aliphatic C–H bonds. In this manifold, a photocatalyst (PCHAT) …

Theoretical models that have been proposed and applied to proton transfer reactions are
reviewed in this work. Simple models, like the Eigen model, Marcus theory and the …

The 320 nm-band photodecarboxylation of aqueous pyruvic acid (PA), a representative of
the α-oxocarboxylic acids widely found in the atmospheric aerosol, yields 2, 3 …

Porphyrin and metalloporphyrin derivatives are at the forefront of the photosensitizers
currently investigated for the photodynamic therapy (PDT) of cancer. Earlier examples …

The study of rates and radical yields in charge-transfer (CT) interactions between organic
triplets and simple anions has been extended to triplets of 1-sulfonate, 1, 5-disulfonate, and …

Abstract The “Marcus Inverted Region”(MIR) is that part of the function of rate constant
versus free energy where a chemical reaction becomes slower as it becomes more …

Recovery of platinum group metals (PGMs) including palladium (Pd), rhodium (Rh), and
ruthenium (Ru) from high-level radioactive liquid waste (HLLW) possesses enormous …

Sunlight can initiate photochemical reactions of organic molecules though direct photolysis,
photosensitization, and indirect processes, often leading to complex radical chemistry that …

Temperature effects on hydrogen atom transfer (HT) and proton-induced electron transfer (p-
ET) via triplet exciplexes in the 1-naphthol-benzophenone (ROH-BP (or> CO)) and …

The microscopic descriptions of electron transfer (ET) reactions given by Marcus theory (MT)
and by the intersecting-state model (ISM) are compared with ab initio calculations on O2/O2 …