Nitroxide-mediated polymerization
Nitroxide-mediated polymerization (NMP) is a controlled/living radical polymerization
(CLRP) technique that enables the design of well-defined, functional and complex …
(CLRP) technique that enables the design of well-defined, functional and complex …
Nitroxide-mediated radical polymerization: limitations and versatility
RB Grubbs - Polymer Reviews, 2011 - Taylor & Francis
Since its introduction in the early 1990s, nitroxide-mediated radical polymerization (NMP)
has been widely adopted for the preparation of a panoply of new polymer architectures …
has been widely adopted for the preparation of a panoply of new polymer architectures …
Telechelic polymers by living and controlled/living polymerization methods
Telechelic polymers, defined as macromolecules that contain two reactive end groups, are
used as cross-linkers, chain extenders, and important building blocks for various …
used as cross-linkers, chain extenders, and important building blocks for various …
A minimal amount of acrylonitrile turns the nitroxide‐mediated polymerization of methyl methacrylate into an almost ideal controlled/living system
J Nicolas, S Brusseau… - Journal of Polymer Science …, 2010 - Wiley Online Library
Nitroxide‐mediated controlled/living free‐radical polymerization of methyl methacrylate
initiated by the SG1‐based alkoxyamine BlocBuilder was successfully performed in bulk at …
initiated by the SG1‐based alkoxyamine BlocBuilder was successfully performed in bulk at …
Ionic liquid containing block copolymer dielectrics: designing for high-frequency capacitance, low-voltage operation, and fast switching speeds
AJ Peltekoff, S Brixi, J Niskanen, BH Lessard - JACS Au, 2021 - ACS Publications
Polymerized ionic liquids (PILs) are a potential solution to the large-scale production of low-
power consuming organic thin-film transistors (OTFTs). When used as the device gating …
power consuming organic thin-film transistors (OTFTs). When used as the device gating …
Facile synthesis of innocuous comb-shaped polymethacrylates with PEG side chains by nitroxide-mediated radical polymerization in hydroalcoholic solutions
M Chenal, S Mura, C Marchal, D Gigmes… - …, 2010 - ACS Publications
The nitroxide-mediated copolymerization of poly (ethylene glycol) methyl ether methacrylate
(MePEGMA) with a small amount of acrylonitrile using an SG1-based alkoxyamine initiator …
(MePEGMA) with a small amount of acrylonitrile using an SG1-based alkoxyamine initiator …
Metal‐free synthesis of responsive polymers: Cloud point tuning by controlled “click” reaction
Nitroxide‐mediated radical polymerization has been used for the preparation of
pentafluorostyrene (PFS) homopolymers and random copolymers of PFS and oligo …
pentafluorostyrene (PFS) homopolymers and random copolymers of PFS and oligo …
Fluorescent, Thermoresponsive Oligo(ethylene glycol) Methacrylate/9-(4-Vinylbenzyl)-9H-carbazole Copolymers Designed with Multiple LCSTs via Nitroxide …
BH Lessard, EJY Ling, M Marić - Macromolecules, 2012 - ACS Publications
9-(4-Vinylbenzyl)-9 H-carbazole (VBK) was used as the “controlling” comonomer for
nitroxide mediated polymerization with 10 mol% SG1 free nitroxide relative to BlocBuilder …
nitroxide mediated polymerization with 10 mol% SG1 free nitroxide relative to BlocBuilder …
Nitroxide-mediated polymerization of methyl methacrylate and styrene with new alkoxyamines from 4-nitrophenyl 2-methylpropionat-2-yl radicals
The N-phenylalkoxyamine N-(1-methyl-(1-(4-nitrophenoxy) carbonyl) ethoxy)-N-(1-methyl-(1-
(4-nitrophenoxy) carbonyl) ethyl) benzenamine (1) was prepared by the addition of 4 …
(4-nitrophenoxy) carbonyl) ethyl) benzenamine (1) was prepared by the addition of 4 …
Nitroxide-mediated copolymerization of methacrylic acid with sodium 4-styrene sulfonate: Towards new water-soluble macroalkoxyamines for the synthesis of …
S Brusseau, J Belleney, S Magnet, L Couvreur… - Polymer …, 2010 - pubs.rsc.org
The SG1-mediated copolymerization of methacrylic acid (MAA) and 4-styrene sulfonate (SS)
was studied in dimethylsulfoxide solution at 76° C, first, to determine the reactivity ratios in …
was studied in dimethylsulfoxide solution at 76° C, first, to determine the reactivity ratios in …