Molecular magnetic materials based on 4d and 5d transition metals

XY Wang, C Avendaño, KR Dunbar - Chemical Society Reviews, 2011 - pubs.rsc.org
The study of paramagnetic compounds based on 4d and 5d transition metals is an emerging
research topic in the field of molecular magnetism. An essential driving force for the interest …

The impact of ligands upon topology and functionality of octacyanidometallate-based assemblies

B Nowicka, T Korzeniak, O Stefańczyk… - Coordination Chemistry …, 2012 - Elsevier
Complete overview of octacyanidometallate polymetallic assemblies is presented from a
novel viewpoint of the importance of incorporated ligands. The ligands are classified …

Enhanced Ion Anisotropy by Nonconventional Coordination Geometry: Single-Chain Magnet Behavior for a [{FeIIL}2{NbIV(CN)8}] Helical Chain Compound Designed with …

TS Venkatakrishnan, S Sahoo, N Bréfuel… - Journal of the …, 2010 - ACS Publications
Nonconventional heptacoordination in combination with efficient magnetic exchange
coupling is shown to yield a 1-D heteronuclear {FeIINbIV} compound with remarkable …

Modular approach towards functional multimetallic coordination clusters

J Kobylarczyk, E Kuzniak, M Liberka, S Chorazy… - Coordination Chemistry …, 2020 - Elsevier
Polynuclear coordination clusters (PCCs) provide considerable design capabilities towards
various functions based on structural non-rigidity and spin state transitions, optical …

Hetero-Metallic {3d-4f-5d} Complexes: Preparation and Magnetic Behavior of Trinuclear [(LMe2Ni−Ln){W(CN)8}] Compounds (Ln = Gd, Tb, Dy, Ho, Er, Y; LMe2 …

JP Sutter, S Dhers, R Rajamani, S Ramasesha… - Inorganic …, 2009 - ACS Publications
Assembling bimetallic {Ni− Ln} 3+ units and {W (CN) 8} 3− is shown to be an efficient route
toward heteronuclear {3d-4f-5d} compounds. The reaction of either the binuclear [{LMe2Ni …

Magnetic clusters based on octacyanidometallates

D Pinkowicz, R Podgajny, B Nowicka… - Inorganic Chemistry …, 2015 - pubs.rsc.org
Octacyanidometallates make an important branch of cyanide-based molecular magnets that
not only follow the trends in modern magnetochemistry and materials science but also have …

pH-Dependent Syntheses and Crystal Structures of a Series of Organic− Inorganic Hybrids Constructed from Keggin or Wells− Dawson Polyoxometalates and Silver …

H Yang, S Gao, J Lü, B Xu, J Lin, R Cao - Inorganic chemistry, 2010 - ACS Publications
A series of silver complexes of polyoxometalates (POMs), formulated as,[Ag2 (4, 4′-bpy) 2
(4, 4′-Hbpy)(H2O)][PW12O40](4, 4′-bpy= 4, 4′-bipyridine, 1),[Ag4 (4, 4′-bpy) 4][4, 4 …

Multifunctional Magnetic Molecular {[MnII(urea)2(H2O)]2[NbIV(CN)8]}n System: Magnetization-Induced SHG in the Chiral Polymorph

D Pinkowicz, R Podgajny, W Nitek, M Rams… - Chemistry of …, 2011 - ACS Publications
Incorporation of urea molecules into the magnetic system MnII-[NbIV (CN) 8] results in
formation of two magnetic polymorphs {[MnII (H2O)(urea) 2] 2 [NbIV (CN) 8]} n chiral α and …

Double switching of a magnetic coordination framework through intraskeletal molecular rearrangement

D Pinkowicz, R Podgajny, B Gaweł, W Nitek… - Angewandte …, 2011 - infona.pl
Auf den Stufen zum Olymp: Ein Mn 2 Nb‐Koordinationsnetzwerk zeigt ein ausgeprägtes
Schalten der Curie‐Temperatur mit zwei wohldefinierten Stufen, wobei in der wasserfreien …

Three‐Axis Anisotropic Exchange Coupling in the Single‐Molecule Magnets NEt4[MnIII2(5‐Brsalen)2(MeOH)2MIII(CN)6] (M=Ru, Os)

J Dreiser, KS Pedersen, A Schnegg… - … A European Journal, 2013 - Wiley Online Library
We have investigated the single‐molecule magnets [MnIII2 (5‐Brsalen) 2 (MeOH) 2MIII (CN)
6] NEt4 (M= Os (1) and Ru (2); 5‐Brsalen= N, N′‐ethylenebis (5‐bromosalicylidene) …