Hydroamination, the addition of an N–H bond across a C–C multiple bond, is a reaction with
a great synthetic potential. Important advances have been made in the last decades …

The catalyst-directed divergent synthesis, commonly termed as “divergent catalysis”, has
emerged as a promising technique as it allows chartering of structurally distinct products …

For more than a decade the innovative field of homogeneous catalysis by gold was
dominated by the interaction of the substrate molecule with one gold center, in most cases in …

The last two decades have seen a veritable explosion in the use of gold (I) complexes
bearing N-heterocyclic carbene (NHC) and phosphine (PR3) ligands. Both ligand families …

Artificial metalloenzymes result from anchoring an organometallic catalyst within an
evolvable protein scaffold. Thanks to its dimer of dimers quaternary structure, streptavidin …

The latest advances in the field of gold-catalyzed divergent synthesis of carbo-and
heterocycles are highlighted in this Perspective. These gold-catalyzed reactions, which can …

Chemical tools that enable a catalytic reaction to selectively and efficiently yield different
products will allow charting of wider chemical space. In ligand‐directed divergent synthesis …

An overview of the current state of mechanistic understanding of gold-catalyzed
intermolecular alkyne hydrofunctionalization reactions is presented. Moving from the …

A synthetic method to prepare tricyclic bridged heptenones and hexenones from gold (I)-
catalyzed double cycloisomerization of 1, 11-dien-3, 9-diyne benzoates is described. A …

This review summarizes the isolated organometallic compounds which represent analogues
of intermediates of homogeneous gold-catalyzed organic reactions or authentic …