Transition‐metal‐catalyzed hydroformylation reactions constitute one of the most powerful
tools for C C bond formation in organic synthesis and represent an outstanding example of …

Looking backward at the beginning of the new millennium, dramatic progress in the scope
and the accuracy of quantum chemistry can be seen, particulary when current applications …

The bite angle effect on the rhodium diphosphine catalyzed hydroformylation was
investigated in detail. A series of xantphos-type ligands with natural bite angles ranging from …

The chemistry of palladium and platinum is one of the most extensive and versatile fields of
chemistry. This results from the fact that these two metals can very easily form adducts with …

The advantages of using two different metals to enhance some desired property has been
recognized by different cultures dating from around 1500 BC in Europe to much earlier (as …

The reaction of 1‐alkenes with carbon monoxide and hydrogen in the presence of a catalyst
gives the corresponding homologous aldehydes. The discovery of this reaction was made …

A novel series of ligands (1− 10) that induce wide bite angles (106°< βn< 131°) has been
synthesized. Compared to the xantphos series (eg, 13 versus 5), the introduction of the …

The influence of transition metal complexes as catalysts upon the activity and selectivity of
hydroformylation reactions has been extensively investigated during the last decades …

Die Übergangsmetall‐katalysierte Hydroformylierung ist eine der effizientesten Methoden
zur C‐C‐Bindungsknüpfung in der organischen Synthesechemie und repräsentiert eines …

An efficient implementation of a quantum mechanical/molecular mechanics (QM/MM) Monte
Carlo (MC) simulation of liquid water is presented. The auto-correlation function of the …