Modern history of organic conductors: An overview

T Naito - Crystals, 2021 - mdpi.com
This short review article provides the reader with a summary of the history of organic
conductors. To retain a neutral and objective point of view regarding the history …

Hidden ligand noninnocence: A combined spectroscopic and computational perspective

B Mondal, S Ye - Coordination Chemistry Reviews, 2020 - Elsevier
Ligand noninnocence has been well-established for transition metal complexes containing
diatomics such as NO and O 2, and bidentate chelates like quinones/semiquinones …

Macrocyclic receptor for precious gold, platinum, or palladium coordination complexes

W Liu, AG Oliver, BD Smith - Journal of the American Chemical …, 2018 - ACS Publications
Two macrocyclic tetralactam receptors are shown to selectively encapsulate anionic, square-
planar chloride and bromide coordination complexes of gold (III), platinum (II), and …

Syntheses and characterization of several nickel bis (dithiolene) complexes with strong and broad Near-IR absorption

Q Miao, J Gao, Z Wang, H Yu, Y Luo, T Ma - Inorganica Chimica Acta, 2011 - Elsevier
Several nickel bis (dithiolene) complexes with strong and broad absorptions in the Near-IR
(NIR) region (700–1100nm) were synthesized by using green and simple synthetic routes …

Gold(iii) bis(dithiolene) complexes: from molecular conductors to prospective anticancer, antimicrobial and antiplasmodial agents

D Fontinha, SA Sousa, TS Morais, M Prudêncio… - Metallomics, 2020 - academic.oup.com
The anticancer, antimicrobial and antiplasmodial activities of six gold (iii) bis (dithiolene)
complexes were studied. Complexes 1–6 showed relevant anticancer properties against …

The quest for single component molecular metals within neutral transition metal complexes

MFG Velho, RAL Silva, D Belo - Journal of Materials Chemistry C, 2021 - pubs.rsc.org
Twenty years ago, the molecular materials community accomplished a major breakthrough
with the report of the first single component molecular metal (SCMM). Previously it was …

Nanospheres of copper (iii) 1, 2-dicarbomethoxy-1, 2-dithiolate and its composite with water soluble carbon nanotubes

KM Tripathi, A Begum, SK Sonkar… - New Journal of Chemistry, 2013 - pubs.rsc.org
We report here the synthesis and structural characterization of a new discrete bis-dithiolene
complex,[PPh4][Cu (DMED) 2](1; DMED= 1, 2-dicarbomethoxy-1, 2-dithiolate), involving the …

Copper-catalyzed annulative coupling of S, S-disubstituted enones with diazo compounds to access highly functionalized thiophene derivatives

Y He, J Lou, P Wu, YG Zhou, Z Yu - The Journal of Organic …, 2019 - ACS Publications
An efficient protocol toward fully substituted thiophenes and thieno [2, 3-b] thiophenes has
been developed through CuCl2-catalyzed annulative coupling of S, S-disubstituted enones …

A single-component conductor based on a radical gold dithiolene complex with alkyl-substituted thiophene-2, 3-dithiolate ligand

T Higashino, O Jeannin, T Kawamoto, D Lorcy… - Inorganic …, 2015 - ACS Publications
Alkyl-substituted thiophene-2, 3-dithiolate ligands are prepared through a Thio-Claisen
rearrangement of 4, 5-bis (propargylthio)-1, 3-dithiole-2-thione derivatives. The two novel …

Spin-orbit coupling and strong electronic correlations in cyclic molecules

AL Khosla, AC Jacko, J Merino, BJ Powell - Physical Review B, 2017 - APS
In atoms spin-orbit coupling (SOC) cannot raise the angular momentum above a maximum
value or lower it below a minimum. Here we show that this need not be the case in materials …