Dynamic reconstitution between copper single atoms and clusters for electrocatalytic urea synthesis

X Wei, Y Liu, X Zhu, S Bo, L Xiao, C Chen… - Advanced …, 2023 - Wiley Online Library
Abstract Electrocatalytic C N coupling between carbon dioxide and nitrate has emerged to
meet the comprehensive demands of carbon footprint closing, valorization of waste, and …

Structure of the catalytically active copper–ceria interfacial perimeter

A Chen, X Yu, Y Zhou, S Miao, Y Li, S Kuld… - Nature Catalysis, 2019 - nature.com
Cu/CeO2 catalysts are highly active for the low-temperature water–gas shift—a core reaction
in syngas chemistry for tuning the H2/CO/CO2 proportions in feed streams—but the direct …

Adsorption and activation of molecular oxygen over atomic copper (I/II) site on ceria

L Kang, B Wang, Q Bing, M Zalibera, R Büchel… - Nature …, 2020 - nature.com
Supported atomic metal sites have discrete molecular orbitals. Precise control over the
energies of these sites is key to achieving novel reaction pathways with superior selectivity …

Construction of active site in a sintered copper–ceria nanorod catalyst

WZ Yu, WW Wang, SQ Li, XP Fu, X Wang… - Journal of the …, 2019 - ACS Publications
The construction of stable active site in nanocatalysts is of great importance but is a
challenge in heterogeneous catalysis. Unexpectedly, coordination-unsaturated and …

New insights into the single-atom-decorated Zr2CO2 (MXene) as an efficient catalyst for CO oxidation in incomplete combustion gas

B Cai, J Zhou, D Li, Z Ao - Applied Surface Science, 2022 - Elsevier
To design novel non-noble metal nano-catalysts for CO oxidation at low temperature and
further understand the mechanism of CO oxidation in incomplete combustion gas (mainly …

First Principles Study on the Mechanism of Nitrobenzene Hydrogenation by a Ni1/CeO2-x(111) Single-Atom Catalyst

H Wang, C Yue, J Du, M Pu, M Lei - The Journal of Physical …, 2023 - ACS Publications
Ceria (CeO2) exhibits superior catalytic activity and selectivity in the hydrogenation of
nitrobenzene via combination with other transition metals. However, the reaction mechanism …

Effect of Cu/CeO2 catalyst preparation methods on their characteristics for low temperature water− gas shift reaction: a detailed study

SY Ahn, HS Na, KW Jeon, YL Lee, KJ Kim, JO Shim… - Catalysis Today, 2020 - Elsevier
To investigate the effect of Cu/CeO 2 catalysts preparation methods for low temperature
water− gas shift reaction, Cu/CeO 2 catalysts were prepared with various impregnation …

Machine learning powered by principal component descriptors as the key for sorted structural fit of XANES

A Martini, AA Guda, SA Guda, AL Bugaev… - Physical Chemistry …, 2021 - pubs.rsc.org
Modern synchrotron radiation sources and free electron laser made X-ray absorption
spectroscopy (XAS) an analytical tool for the structural analysis of materials under in situ or …

A DFT study on methanol decomposition over single atom Pt/CeO 2 catalysts: the effect of the position of Pt

H Lu, Y Zhong, Y Jie, P Yin, XJ Zhao… - Physical Chemistry …, 2023 - pubs.rsc.org
Pt/CeO2 catalysts exhibit excellent catalytic performance for the methanol dehydrogenation
(MD) reaction. In this work, MD reactions on three systems of Pt1/CeO2 (110)), Pt7/CeO2 …

CeO 2 (111) electronic reducibility tuned by ultra-small supported bimetallic Pt–Cu clusters

LO Paz-Borbón, F Buendía, IL Garzón… - Physical Chemistry …, 2019 - pubs.rsc.org
Controlling Ce4+ to Ce3+ electronic reducibility in a rare-earth binary oxide such as CeO2
has enormous applications in heterogeneous catalysis, where a profound understanding of …