Nitrogen fixation via splitting into nitrido complexes
SJK Forrest, B Schluschaß, EY Yuzik-Klimova… - Chemical …, 2021 - ACS Publications
The large carbon footprint of the Haber–Bosch process, which provides ammonia for
fertilizers but also the feedstock for all nitrogenous commercial products, has fueled the …
fertilizers but also the feedstock for all nitrogenous commercial products, has fueled the …
Activation of dinitrogen by polynuclear metal complexes
Activation of dinitrogen plays an important role in daily anthropogenic life, and the processes
by which this fixation occurs have been a longstanding and significant research focus within …
by which this fixation occurs have been a longstanding and significant research focus within …
Breaking scaling relations to achieve low-temperature ammonia synthesis through LiH-mediated nitrogen transfer and hydrogenation
Ammonia synthesis under mild conditions is a goal that has been long sought after. Previous
investigations have shown that adsorption and transition-state energies of intermediates in …
investigations have shown that adsorption and transition-state energies of intermediates in …
Nickel hydride complexes
NA Eberhardt, H Guan - Chemical reviews, 2016 - ACS Publications
Nickel hydride complexes, defined herein as any molecules bearing a nickel hydrogen
bond, are crucial intermediates in numerous nickel-catalyzed reactions. Some of them are …
bond, are crucial intermediates in numerous nickel-catalyzed reactions. Some of them are …
Complexes of Ni (I): a “rare” oxidation state of growing importance
Nickel plays an important role in areas as diverse as metallurgy, magnetism and biology as
well as in chemical applications such as the catalytic transformation of organic substrates …
well as in chemical applications such as the catalytic transformation of organic substrates …
The chemistry of univalent metal β-diketiminates
YC Tsai - Coordination Chemistry Reviews, 2012 - Elsevier
The easily electronically and sterically tunable β-diketiminates are widely used auxiliary
ligands for the creation of a wide range of metal complexes with various oxidation states in …
ligands for the creation of a wide range of metal complexes with various oxidation states in …
Metal–dioxygen and metal–dinitrogen complexes: where are the electrons?
PL Holland - Dalton transactions, 2010 - pubs.rsc.org
Transition-metal complexes of O2 and N2 play an important role in the environment,
chemical industry, and metalloenzymes. This Perspective compares and contrasts the …
chemical industry, and metalloenzymes. This Perspective compares and contrasts the …
Ni (I)–X complexes bearing a bulky α-diimine ligand: synthesis, structure, and superior catalytic performance in the hydrogen isotope exchange in pharmaceuticals
The synthesis and spectroscopic characterization of a family of Ni–X (X= Cl, Br, I, H)
complexes supported by the bulky α-diimine chelate N, N′-bis (1 R, 2 R, 3 R, 5 S)-(−) …
complexes supported by the bulky α-diimine chelate N, N′-bis (1 R, 2 R, 3 R, 5 S)-(−) …
Donor‐Acceptor Activation of Carbon Dioxide
M Pérez‐Jiménez, H Corona… - … A European Journal, 2023 - Wiley Online Library
The activation and functionalization of carbon dioxide entails great interest related to its
abundance, low toxicity and associated environmental problems. However, the inertness of …
abundance, low toxicity and associated environmental problems. However, the inertness of …
A d10 Ni–(H2) Adduct as an Intermediate in HH Oxidative Addition across a NiB Bond
Abstract Bifunctional E H activation offers a promising approach for the design of two‐
electron‐reduction catalysts with late first‐row metals, such as Ni. To this end, we have been …
electron‐reduction catalysts with late first‐row metals, such as Ni. To this end, we have been …