Open-shell radicals are usually thermodynamically and kinetically unstable due to their
incompletely satisfied valency. However, the rapid development of radical chemistry in the …

Incorporation of main group elements into the π-conjugated frameworks is a sophisticated
strategy to alter the fundamental nature of the parent conjugated π-systems, giving rise to …

Abstract Discovered in 2005, cyclic (alkyl)(amino) carbenes (CAACs) are among the most
nucleophilic (σ donating) and also electrophilic (π‐accepting) stable carbenes known to …

Single-molecule topological insulators are promising candidates as conducting wires over
nanometre length scales. A key advantage is their ability to exhibit quasi-metallic transport …

Most organic semiconductors have closed-shell electronic structures, however, studies have
revealed open-shell character emanating from design paradigms such as narrowing the …

Aromaticity is an important concept to understand the stability and physical properties of π-
conjugated molecules. Recent studies on pro-aromatic and anti-aromatic molecules …

In this Feature Article, we highlight our recent efforts toward stable open-shell singlet
diradicaloids and polyradicaloids. A brief review on the historical works in the area is …

Developing open-shell singlet (OS) diradicals with high luminescent properties and
exceptional single-molecule magnetoluminescence (ML) performance is extremely …

Organic materials with radical characteristics are gaining increasing attention, due to their
potential implications in highly efficient utilization of solar energy. Manipulating …

It is very challenging to obtain stable room‐temperature luminescent open‐shell singlet
diradicals. Herein we report the first stable Müller's hydrocarbon TTM‐PhTTM with …