Transition-metal catalyzed reactions that are able to construct complex aliphatic amines from
simple, readily available feedstocks have become a cornerstone of modern synthetic …

Abstract Transition-metal-catalysed, non-enzymatic transformations of C–H and C= C bonds
to C–N bonds through nitrene transfer (NT) are powerful synthetic tools to prepare valuable …

Catalytic transformation of ubiquitous C–H bonds into valuable C–N bonds offers an efficient
synthetic approach to construct N-functionalized molecules. Over the last few decades …

Recent advances in transition metal-catalyzed C–H bond functionalization have profoundly
impacted synthetic strategy. Since organic substrates typically contain several chemically …

Intramolecular insertion of metal nitrenes into carbon-hydrogen bonds to form γ-lactam rings
has traditionally been hindered by competing isocyanate formation. We report the …

Silver, known and utilized since ancient times, is a coinage metal, which has been widely
used for various organic transformations in the past few decades. Currently, the silver …

The Cδ− H amination of unactivated, secondary C− H bonds to form a broad range of
functionalized pyrrolidines has been developed by a triiodide (I3−)‐mediated strategy. By in …

Control of enantioselectivity remains a major challenge in radical chemistry. The emergence
of metalloradical catalysis (MRC) offers a conceptually new strategy for addressing this and …

Racemization is considered to be an intrinsic stereochemical feature of free radical
chemistry as can be seen in traditional radical halogenation reactions of optically active …

Catalytic C–H amination reactions enable direct functionalization of non-activated C (sp3)–H
bonds with high levels of regio-, chemo-and stereoselectivity. As a powerful tool to unlock …