Non-conjugated electrochromic supercapacitors with atom-economic arylamine-based AB 2-polyamides
YJ Shao, YJ Cho, HL Li, CC Hu, GS Liou - Journal of Materials …, 2024 - pubs.rsc.org
A highly atom-economic AB2-type hyperbranched polyamide (HPA) derived from arylamine
monomers was judiciously designed and prepared. This electroactive HPA was further end …
monomers was judiciously designed and prepared. This electroactive HPA was further end …
Automated Calibration for Rapid Optical Spectroscopy Sensor Development for Online Monitoring
HB Andrews, LR Sadergaski - ACS sensors, 2024 - ACS Publications
An automated platform has been developed to assist researchers in the rapid development
of optical spectroscopy sensors to quantify species from spectral data. This platform …
of optical spectroscopy sensors to quantify species from spectral data. This platform …
Comparing Sensor Fusion and Multimodal Chemometric Models for Monitoring U (VI) in Complex Environments Representative of Irradiated Nuclear Fuel
LR Sadergaski, HB Andrews, BA Wilson - Analytical Chemistry, 2024 - ACS Publications
Optical sensors and chemometric models were leveraged for the quantification of uranium
(VI)(0–100 μg mL–1), europium (0–150 μg mL–1), samarium (0–250 μg mL–1) …
(VI)(0–100 μg mL–1), europium (0–150 μg mL–1), samarium (0–250 μg mL–1) …
Quantifying neptunium oxidation states in nitric acid through spectroelectrochemistry and chemometrics
Controlled-potential in situ thin-layer spectropotentiometry was leveraged to generate
visible/near-infrared (VIS/NIR) absorption spectral data sets for the development of …
visible/near-infrared (VIS/NIR) absorption spectral data sets for the development of …
Leveraging design of experiments to build chemometric models for the quantification of uranium (VI) and HNO3 by Raman spectroscopy
LR Sadergaski, JD Einkauf, LH Delmau… - Frontiers in Nuclear …, 2024 - frontiersin.org
Partial least squares regression (PLSR) and support vector regression (SVR) models were
optimized for the quantification of U (VI)(10–320 g L− 1) and HNO3 (0.6–6 M) by Raman …
optimized for the quantification of U (VI)(10–320 g L− 1) and HNO3 (0.6–6 M) by Raman …
Remote Sensing of Nitric Acid and Temperature via Design of Experiments, Chemometrics, and Raman Spectroscopy
This study presents an effective method for the quantification of nitric acid (0.1–9 M) and the
temperature (20–60° C) through optimal experimental design, chemometrics, and Raman …
temperature (20–60° C) through optimal experimental design, chemometrics, and Raman …
Hierarchical Modeling to Enhance Spectrophotometry Measurements—Overcoming Dynamic Range Limitations for Remote Monitoring of Neptunium
HB Andrews, LR Sadergaski - Chemosensors, 2023 - mdpi.com
A robust hierarchical model has been demonstrated for monitoring a wide range of
neptunium concentrations (0.75–890 mM) and varying temperatures (10–80° C) using …
neptunium concentrations (0.75–890 mM) and varying temperatures (10–80° C) using …
Leveraging Calibration Transfer Techniques for Remote Monitoring of Samarium and Europium in LiCl Using Laser-Induced Florescence Spectroscopy for …
HB Andrews, J Moon… - Industrial & Engineering …, 2024 - ACS Publications
Radioisotope production relies on complex chemical processes that must be performed in
radiological hot cells or glove boxes because of the radioactive and otherwise hazardous …
radiological hot cells or glove boxes because of the radioactive and otherwise hazardous …
Insights into Tetravalent Np Speciation in HNO3 through Spectroelectrochemistry and Multivariate Analysis
In situ optical spectroscopy, spectropotentiometry, and multivariate analysis were applied to
the Np (IV) nitrate system to better understand speciation and quantify HNO3 concentration …
the Np (IV) nitrate system to better understand speciation and quantify HNO3 concentration …
Novel Calibration Approach for Monitoring Aerosol Hydrogen Isotopes Using Laser-Induced Breakdown Spectroscopy for Molten Salt Reactor Off-Gas Streams
HB Andrews, J McFarlane - Sensors, 2023 - mdpi.com
Online monitoring is a key challenge for the continued development of molten salt reactor
(MSR) technology. Laser-induced breakdown spectroscopy (LIBS) has previously been …
(MSR) technology. Laser-induced breakdown spectroscopy (LIBS) has previously been …