[HTML][HTML] Single-Molecule Magnets: From Mn12-ac to dysprosium metallocenes, a travel in time

A Zabala-Lekuona, JM Seco, E Colacio - Coordination Chemistry Reviews, 2021 - Elsevier
The discovery of the first Single-Molecule Magnet, Mn12-ac, in 1993 changed the
perspective of how information can be stored. The current bit, occupying few hundreds of …

[HTML][HTML] Electronic structure and magnetic anisotropy design of functional metal complexes

A Raza, M Perfetti - Coordination Chemistry Reviews, 2023 - Elsevier
Chemical guidelines to target a well-defined electronic structure and magnetic anisotropy
are of primary importance in physics, chemistry and biology. Our literature overview …

A terminal neptunium (V)–mono (oxo) complex

MS Dutkiewicz, CAP Goodwin, M Perfetti, AJ Gaunt… - Nature Chemistry, 2022 - nature.com
Neptunium was the first actinide element to be artificially synthesized, yet, compared with its
more famous neighbours uranium and plutonium, is less conspicuously studied. Most …

Pentagonal bipyramidal Ln (III) complexes containing an axial phosphine oxide ligand: Field-induced single-ion magnetism behavior of the Dy (III) analogues

P Kalita, N Ahmed, AK Bar, S Dey, A Jana… - Inorganic …, 2020 - ACS Publications
A series of neutral homologous complexes [(L) Ln (Cy3PO) Cl]{where Ln= Gd (1), Tb (2), Dy
(3), and Er (5)} and [(L) Dy (Ph3PO) Cl](4)[H2L= 2, 6-diacetylpyridine bis-benzoylhydrazone] …

Perplexing EPR Signals from 5f36d1 U(II) Complexes

JC Wedal, WNG Moore, WW Lukens… - Inorganic …, 2024 - ACS Publications
Metal complexes with unpaired electrons in orbitals of different angular momentum quantum
numbers (eg., f and d orbitals) are unusual and opportunities to study the interactions among …

Actinide-based single-molecule magnets: alone or in a group?

M Liu, XH Peng, FS Guo, ML Tong - Inorganic Chemistry Frontiers, 2023 - pubs.rsc.org
In recent years, very significant progress has been made in single-molecule magnets
(SMMs), and one of the major milestone works is the hysteresis blocking temperature …

Spectroscopic techniques to probe magnetic anisotropy and spin–phonon coupling in metal complexes

AT Hand, BD Watson-Sanders, ZL Xue - Dalton Transactions, 2024 - pubs.rsc.org
Magnetism of molecular quantum materials such as single-molecule magnets (SMMs) has
been actively studied for potential applications in the new generation of high-density data …

Exploring the high-temperature frontier in molecular nanomagnets: from lanthanides to actinides

L Escalera-Moreno, JJ Baldoví, A Gaita-Ariño… - Inorganic …, 2019 - ACS Publications
Molecular nanomagnets based on mononuclear metal complexes, also known as single-ion
magnets (SIMs), are crossing challenging boundaries in molecular magnetism. From an …

Uranocenium: Synthesis, structure, and chemical bonding

FS Guo, YC Chen, ML Tong… - Angewandte …, 2019 - Wiley Online Library
Abstraction of iodide from [(η5‐C5iPr5) 2UI](1) produced the cationic uranium (III)
metallocene [(η5‐C5iPr5) 2U]+(2) as a salt of [B (C6F5) 4]−. The structure of 2 consists of …

Uranium going the soft way: low-valent uranium (III) coordinated to an arene-anchored tris-thiophenolate ligand

D Pividori, ME Miehlich, B Kestel… - Inorganic …, 2021 - ACS Publications
The synthesis of a tripodal, S-based ligand, namely the mesitylene-anchored, tris-
thiophenolate-functionalized (mes (Me, AdArS) 3) 3–(1) 3–, and its coordination chemistry …