Supramolecular luminescent sensors
TL Mako, JM Racicot, M Levine - Chemical reviews, 2018 - ACS Publications
There is great need for stand-alone luminescence-based chemosensors that exemplify
selectivity, sensitivity, and applicability and that overcome the challenges that arise from …
selectivity, sensitivity, and applicability and that overcome the challenges that arise from …
Exploiting non-covalent π interactions for catalyst design
Molecular recognition, binding and catalysis are often mediated by non-covalent interactions
involving aromatic functional groups. Although the relative complexity of these so-called π …
involving aromatic functional groups. Although the relative complexity of these so-called π …
σ-Hole bond vs π-hole bond: a comparison based on halogen bond
H Wang, W Wang, WJ Jin - Chemical reviews, 2016 - ACS Publications
The σ-hole and π-hole are the regions with positive surface electrostatic potential on the
molecule entity; the former specifically refers to the positive region of a molecular entity …
molecule entity; the former specifically refers to the positive region of a molecular entity …
The bright future of unconventional σ/π‐hole interactions
Non‐covalent interactions play a crucial role in (supramolecular) chemistry and much of
biology. Supramolecular forces can indeed determine the structure and function of a host …
biology. Supramolecular forces can indeed determine the structure and function of a host …
A million crystal structures: The whole is greater than the sum of its parts
R Taylor, PA Wood - Chemical reviews, 2019 - ACS Publications
The founding in 1965 of what is now called the Cambridge Structural Database (CSD) has
reaped dividends in numerous and diverse areas of chemical research. Each of the million …
reaped dividends in numerous and diverse areas of chemical research. Each of the million …
Putting anion–π interactions into perspective
A Frontera, P Gamez, M Mascal… - Angewandte Chemie …, 2011 - Wiley Online Library
Supramolecular chemistry is a field of scientific exploration that probes the relationship
between molecular structure and function. It is the chemistry of the noncovalent bond, which …
between molecular structure and function. It is the chemistry of the noncovalent bond, which …
Toward a more complete understanding of noncovalent interactions involving aromatic rings
SE Wheeler, JWG Bloom - The journal of physical chemistry A, 2014 - ACS Publications
Noncovalent interactions involving aromatic rings, which include π-stacking interactions,
anion-π interactions, and XH− π interactions, among others, are ubiquitous in chemical and …
anion-π interactions, and XH− π interactions, among others, are ubiquitous in chemical and …
Anion− π interactions with fluoroarenes
M Giese, M Albrecht, K Rissanen - Chemical Reviews, 2015 - ACS Publications
Well-orchestrated noncovalent interactions are fundamental in chemical processes. 1 For
example, the assembly of complementary subunits to form functional aggregates is a …
example, the assembly of complementary subunits to form functional aggregates is a …
Experimental investigation of anion–π interactions–applications and biochemical relevance
M Giese, M Albrecht, K Rissanen - Chemical Communications, 2016 - pubs.rsc.org
Anion–π interactions, intuitively repulsive forces, turned from controversial to a well-
established non-covalent interaction over the past quarter of a century. Within this time frame …
established non-covalent interaction over the past quarter of a century. Within this time frame …
Anion binding involving π-acidic heteroaromatic rings
P Gamez, TJ Mooibroek, SJ Teat… - Accounts of chemical …, 2007 - ACS Publications
Anions are essential species in biological systems and, particularly, in enzyme–substrate
recognition. Therefore, the design and preparation of anion receptors is a topical field of …
recognition. Therefore, the design and preparation of anion receptors is a topical field of …