Understanding specific ion effects and the Hofmeister series

KP Gregory, GR Elliott, H Robertson, A Kumar… - Physical Chemistry …, 2022 - pubs.rsc.org
Specific ion effects (SIE), encompassing the Hofmeister Series, have been known for more
than 130 years since Hofmeister and Lewith's foundational work. SIEs are ubiquitous and …

Water at charged interfaces

G Gonella, EHG Backus, Y Nagata… - Nature Reviews …, 2021 - nature.com
The ubiquity of aqueous solutions in contact with charged surfaces and the realization that
the molecular-level details of water–surface interactions often determine interfacial functions …

Beyond the Hofmeister series: Ion-specific effects on proteins and their biological functions

HI Okur, J Hladílková, KB Rembert, Y Cho… - The Journal of …, 2017 - ACS Publications
Ions differ in their ability to salt out proteins from solution as expressed in the lyotropic or
Hofmeister series of cations and anions. Since its first formulation in 1888, this series has …

The chaotropic effect as an assembly motif in chemistry

KI Assaf, WM Nau - Angewandte Chemie International Edition, 2018 - Wiley Online Library
Following up on scattered reports on interactions of conventional chaotropic ions (for
example, I−, SCN−, ClO4−) with macrocyclic host molecules, biomolecules, and …

Models and mechanisms of Hofmeister effects in electrolyte solutions, and colloid and protein systems revisited

A Salis, BW Ninham - Chemical Society Reviews, 2014 - pubs.rsc.org
Specific effects of electrolytes have posed a challenge since the 1880's. The pioneering
work was that of Franz Hofmeister who studied specific salt induced protein precipitation …

Multiscale modeling of aqueous electric double layers

M Becker, P Loche, M Rezaei, A Wolde-Kidan… - Chemical …, 2023 - ACS Publications
From the stability of colloidal suspensions to the charging of electrodes, electric double
layers play a pivotal role in aqueous systems. The interactions between interfaces, water …

Hofmeister phenomena: an update on ion specificity in biology

P Lo Nostro, BW Ninham - Chemical reviews, 2012 - ACS Publications
Specific ion effects occur everywhere. They occur in bulk solutions and at interfaces
(air/water, oil/water, solid/water, macromolecule/water, etc.). They are even found in …

The Hofmeister series: Specific ion effects in aqueous polymer solutions

SZ Moghaddam, E Thormann - Journal of colloid and interface science, 2019 - Elsevier
Specific ion effects in aqueous polymer solutions have been under active investigation over
the past few decades. The current state-of-the-art research is primarily focused on the …

Protein stabilization and enzyme activation in ionic liquids: specific ion effects

H Zhao - Journal of Chemical Technology & Biotechnology, 2016 - Wiley Online Library
There are still debates on whether the hydration of ions perturbs the water structure, and
what is the degree of such disturbance; therefore, the origin of the Hofmeister effect on …

The electrostatic origins of specific ion effects: quantifying the Hofmeister series for anions

KP Gregory, EJ Wanless, GB Webber, VSJ Craig… - Chemical …, 2021 - pubs.rsc.org
Life as we know it is dependent upon water, or more specifically salty water. Without
dissolved ions, the interactions between biological molecules are insufficiently complex to …