Tsuji-Trost type functionalization of allylic substrates with challenging leaving groups: recent developments
R Ferraccioli, L Pignataro - Current Organic Chemistry, 2015 - ingentaconnect.com
The Review reports the recent developments of palladium-catalyzed nucleophilic
substitution of allylic alcohols and allylic amines used as electrophiles. The poor ability of …
substitution of allylic alcohols and allylic amines used as electrophiles. The poor ability of …
Pd-Catalyzed Direct C–H Alkenylation and Allylation of Azine N-Oxides
A Pd-catalyzed direct C2-alkenylation of azine N-oxides with allyl acetate is disclosed. The
products are formed through an allylation/isomerization cascade process. The use of a tri …
products are formed through an allylation/isomerization cascade process. The use of a tri …
Three-component synthesis of isoquinoline derivatives by a relay catalysis with a single rhodium (III) catalyst
C Zhou, J Jiang, J Wang - Organic letters, 2019 - ACS Publications
A rhodium (III)-catalyzed one-pot three-component reaction of N-methoxybenzamide, α-
diazoester, and alkyne was developed, providing an alternative way to synthesize …
diazoester, and alkyne was developed, providing an alternative way to synthesize …
Efficient synthesis of functionalized dihydroquinolines, quinolines and dihydrobenzo [b] azepine via an iron (III) chloride-catalyzed intramolecular alkyne–carbonyl …
S Jalal, K Bera, S Sarkar, K Paul, U Jana - Organic & Biomolecular …, 2014 - pubs.rsc.org
In this study we have developed an efficient synthesis of 1, 2-dihydroquinoline and
dihydrobenzo [b] azepine derivatives involving the iron (III) chloride intramolecular alkyne …
dihydrobenzo [b] azepine derivatives involving the iron (III) chloride intramolecular alkyne …
Palladium-Catalyzed Dehydrative Cross-Coupling of Allylic Alcohols and N-Heterocycles Promoted by a Bicyclic Bridgehead Phosphoramidite Ligand and an Acid …
A mild and efficient dehydrative cross-coupling reaction between allylic alcohols and N-
heterocycles using palladium catalysis is reported. A bicyclic bridgehead phosphoramidite …
heterocycles using palladium catalysis is reported. A bicyclic bridgehead phosphoramidite …
Ten years advancement in the synthetic applications of 2-bromo-cyclohexenecarbaldehydes and 2-bromobenzaldehydes and derived substrates under palladium …
bromo-cyclohexenecarbaldehyde and 2-bromobenzaldehyde have long been used as an
important tool for the construction loads of compounds of potential biological, medicinal as …
important tool for the construction loads of compounds of potential biological, medicinal as …
NIXANTPHOS: a highly active ligand for palladium catalyzed Buchwald–Hartwig amination of unactivated aryl chlorides
Xantphos is one of the two most common ligands used in palladium catalyzed Buchwald–
Hartwig amination reactions, because of its broad scope and high probability of success. It …
Hartwig amination reactions, because of its broad scope and high probability of success. It …
Palladium-Catalyzed [3+ 2]-C–C/N–C Bond-Forming Annulation
The synthesis of bi-and tricyclic structures incorporating pyrrolidone rings is disclosed,
starting from resonance-stabilized acetamides and cyclic α, β-unsaturated-γ-oxycarbonyl …
starting from resonance-stabilized acetamides and cyclic α, β-unsaturated-γ-oxycarbonyl …
Synthesis of polysubstituted 1, 2-dihydroquinolines and indoles via cascade reactions of arylamines and propargylic alcohols catalyzed by FeCl 3· 6H 2 O
M Shao, Y Wu, Z Feng, X Gu, S Wang - Organic & Biomolecular …, 2016 - pubs.rsc.org
An efficient, environmentally friendly and high-yielding route from inexpensive starting
materials to 1, 2-dihydroquinolines has been developed. This procedure proceeded via a …
materials to 1, 2-dihydroquinolines has been developed. This procedure proceeded via a …
Ruthenium‐Catalyzed Hydroamination of Aminoallenes: an Approach to Vinyl Substituted Heterocycles
G Broggini, G Poli, EM Beccalli, F Brusa… - Advanced Synthesis …, 2015 - Wiley Online Library
Heterosubstituted aminoallenes underwent smooth ruthenium‐catalyzed intramolecular exo‐
hydroamination reactions yielding the corresponding five‐, six‐, or seven‐membered 1, 3 …
hydroamination reactions yielding the corresponding five‐, six‐, or seven‐membered 1, 3 …