Tsuji-Trost type functionalization of allylic substrates with challenging leaving groups: recent developments

R Ferraccioli, L Pignataro - Current Organic Chemistry, 2015 - ingentaconnect.com
The Review reports the recent developments of palladium-catalyzed nucleophilic
substitution of allylic alcohols and allylic amines used as electrophiles. The poor ability of …

Pd-Catalyzed Direct C–H Alkenylation and Allylation of Azine N-Oxides

F Roudesly, LF Veiros, J Oble, G Poli - Organic letters, 2018 - ACS Publications
A Pd-catalyzed direct C2-alkenylation of azine N-oxides with allyl acetate is disclosed. The
products are formed through an allylation/isomerization cascade process. The use of a tri …

Three-component synthesis of isoquinoline derivatives by a relay catalysis with a single rhodium (III) catalyst

C Zhou, J Jiang, J Wang - Organic letters, 2019 - ACS Publications
A rhodium (III)-catalyzed one-pot three-component reaction of N-methoxybenzamide, α-
diazoester, and alkyne was developed, providing an alternative way to synthesize …

Efficient synthesis of functionalized dihydroquinolines, quinolines and dihydrobenzo [b] azepine via an iron (III) chloride-catalyzed intramolecular alkyne–carbonyl …

S Jalal, K Bera, S Sarkar, K Paul, U Jana - Organic & Biomolecular …, 2014 - pubs.rsc.org
In this study we have developed an efficient synthesis of 1, 2-dihydroquinoline and
dihydrobenzo [b] azepine derivatives involving the iron (III) chloride intramolecular alkyne …

Palladium-Catalyzed Dehydrative Cross-Coupling of Allylic Alcohols and N-Heterocycles Promoted by a Bicyclic Bridgehead Phosphoramidite Ligand and an Acid …

K Kang, J Kim, A Lee, WY Kim, H Kim - Organic letters, 2016 - ACS Publications
A mild and efficient dehydrative cross-coupling reaction between allylic alcohols and N-
heterocycles using palladium catalysis is reported. A bicyclic bridgehead phosphoramidite …

Ten years advancement in the synthetic applications of 2-bromo-cyclohexenecarbaldehydes and 2-bromobenzaldehydes and derived substrates under palladium …

M Ghosh, JK Ray - Tetrahedron, 2017 - Elsevier
bromo-cyclohexenecarbaldehyde and 2-bromobenzaldehyde have long been used as an
important tool for the construction loads of compounds of potential biological, medicinal as …

NIXANTPHOS: a highly active ligand for palladium catalyzed Buchwald–Hartwig amination of unactivated aryl chlorides

J Mao, J Zhang, S Zhang, PJ Walsh - Dalton Transactions, 2018 - pubs.rsc.org
Xantphos is one of the two most common ligands used in palladium catalyzed Buchwald–
Hartwig amination reactions, because of its broad scope and high probability of success. It …

Palladium-Catalyzed [3+ 2]-C–C/N–C Bond-Forming Annulation

Y Liu, Z Mao, A Pradal, PQ Huang, J Oble, G Poli - Organic letters, 2018 - ACS Publications
The synthesis of bi-and tricyclic structures incorporating pyrrolidone rings is disclosed,
starting from resonance-stabilized acetamides and cyclic α, β-unsaturated-γ-oxycarbonyl …

Synthesis of polysubstituted 1, 2-dihydroquinolines and indoles via cascade reactions of arylamines and propargylic alcohols catalyzed by FeCl 3· 6H 2 O

M Shao, Y Wu, Z Feng, X Gu, S Wang - Organic & Biomolecular …, 2016 - pubs.rsc.org
An efficient, environmentally friendly and high-yielding route from inexpensive starting
materials to 1, 2-dihydroquinolines has been developed. This procedure proceeded via a …

Ruthenium‐Catalyzed Hydroamination of Aminoallenes: an Approach to Vinyl Substituted Heterocycles

G Broggini, G Poli, EM Beccalli, F Brusa… - Advanced Synthesis …, 2015 - Wiley Online Library
Heterosubstituted aminoallenes underwent smooth ruthenium‐catalyzed intramolecular exo‐
hydroamination reactions yielding the corresponding five‐, six‐, or seven‐membered 1, 3 …