Numerous unsaturated substrate molecules undergo migratory insertion with metal-carbon
bonds. Recent attention has been focused on insertion of CO and alkenes into d8 metal …

Recently, allenes have been widely used as starting materials to synthesize various organic
compounds and polymeric materials, especially through reactions catalyzed by transition …

On a large scale, the dominant method to produce alkyl arenes has been arene alkylation
from arenes and olefins using acid-based catalysis. The addition of arene C–H bonds …

Cationic platinum (II) complexes [(t bpy) Pt (Ph)(L)]+[t bpy= 4, 4′-di-tert-butyl-2, 2′-
bipyridyl; L= THF, NC5F5, or NCMe] catalyze the hydrophenylation of ethylene to generate …

The regiochemistry of the addition of arylpalladium species to styrene and propene has
been studied. It was found that for the reaction of P2Pd (Ph) X the counterion X, the polarity …

Palladium-Catalyzed Oxidative Cross-Coupling Reaction of Arylboronic Acids with
Diazoesters for Stereoselective Synthesis of (E)-α,β-Diarylacrylates | Organic Letters ACS …

Palladium–phenanthroline complexes catalyze both the nitroarene carbonylation reaction
and the amine oxidative carbonylation reaction to give, depending on the conditions …

Propadiene, 3-methyl-1, 2-butadiene (DMA), and 2, 4-dimethyl-2, 3-pentadiene (TMA)
reacted via migratory insertion with both neutral and ionic Pd (R) X (p-An-BIAN)(R= Me (1) …

The PtII complexes [(x bpy) Pt (Ph)(THF)]+(x bpy= 4, 4′-X2-2, 2′-bipyridyl; x= OMe (1a), t
Bu (1b), H (1c), Br (1d), CO2Et (1e) and NO2 (1f)] catalyze the formation of n-propylbenzene …

A series of monoalkyl square-planar complexes of the type [Pt (NN)(CH3)(Me2SO)] PF6 (1−
14), where NN represents chelating diamines or diimines of widely different steric and …