While hydrogen plays an ever-increasing role in modern society, nature has utilized
hydrogen since a very long time as an energy carrier and storage molecule. Among the …

Reduction of oxides and oxoanions of carbon and nitrogen are of great contemporary
importance as they are crucial for a sustainable environment. Substantial research has been …

Over the last 15 years, a plethora of research has provided major insights into the structure
and function of hydrogenase enzymes. This has led to the important development of …

This article sets out to review the chemistry relating to the synthesis of structural and
functional analogues of the three classes of hydrogenases. This chemistry has grown …

This perspective article reviews the recent important progress in electrocatalytic hydrogen
production catalyzed by earth-abundant metal complexes. The catalysts are divided into two …

This tutorial review is aimed at chemical scientists interested in understanding and
exploiting the remarkable catalytic behavior of the hydrogenases. The key structural features …

This article reviews published literature on the electrochemical reduction and oxidation of
complexes containing the Fe2S2 core characteristic of the active site of [FeFe] …

Extended investigation of electrocatalytic generation of dihydrogen using [(μ-1, 2-
benzenedithiolato)][Fe (CO) 3] 2 has revealed that weak acids, such as acetic acid, can be …

This review focuses on electron and proton transfers involving hexacarbonyl and substituted
{2Fe2S} complexes inspired from the active site of the [FeFe]-hydrogenases ([FeFe] …

A short non-exhaustive overview of hexacarbonyl dithiolate di-iron species and of their
substituted derivatives relevant to the chemistry of the di-iron sub-site of the hydrogenase …