Self-assembled stereomutation with supramolecular chirality inversion

G Liu, MG Humphrey, C Zhang, Y Zhao - Chemical Society Reviews, 2023 - pubs.rsc.org
Supramolecular chirality is involved not only in biological events such as gene
communication, replication, and enzyme catalysis but also in artificial self-assembly systems …

Supramolecular helical systems: helical assemblies of small molecules, foldamers, and polymers with chiral amplification and their functions

E Yashima, N Ousaka, D Taura, K Shimomura… - Chemical …, 2016 - ACS Publications
In this review, we describe the recent advances in supramolecular helical assemblies
formed from chiral and achiral small molecules, oligomers (foldamers), and helical and …

[HTML][HTML] Stimuli-responsive synthetic helical polymers

M Lago-Silva, M Fernández-Míguez… - Chemical Society …, 2024 - pubs.rsc.org
Synthetic dynamic helical polymers (supramolecular and covalent) and foldamers share the
helix as a structural motif. Although the materials are different, these systems also share …

Control on dimensions and supramolecular chirality of self-assemblies through light and metal ions

G Liu, J Sheng, WL Teo, G Yang, H Wu… - Journal of the …, 2018 - ACS Publications
Precise control over helical chirality and dimensions of molecular self-assemblies, a
remaining challenge for both chemists and materials scientists, is the key to manipulate the …

Metal‐Ion‐Mediated Supramolecular Chirality of l‐Phenylalanine Based Hydrogels

F Wang, CL Feng - Angewandte Chemie, 2018 - Wiley Online Library
For chiral hydrogels and related applications, one of the critical issues is how to control the
chirality of supramolecular systems in an efficient way, including easy operation, efficient …

pseudo[1]Catenane-Type Pillar[5]thiacrown Whose Planar Chiral Inversion is Triggered by Metal Cation and Controlled by Anion

E Lee, H Ju, IH Park, JH Jung, M Ikeda… - Journal of the …, 2018 - ACS Publications
Chiral inversion of single molecules has been a challenging task because chirality
information controls structures and functions of various molecules, artificial nanostructures …

Stimuli-responsive chirality inversion of metallohelices and related dynamic metal complexes

S Akine, H Miyake - Coordination Chemistry Reviews, 2022 - Elsevier
Metal-coordination structures, which contain coordination bonds with a dynamic nature, are
generally useful as a platform for stimuli-responsive molecules and materials. This feature …

Chirality Supramolecular Systems: Helical Assemblies, Structure Designs, and Functions

S Jia, T Tao, Y Xie, L Yu, X Kang, Y Zhang, W Tang… - Small, 2024 - Wiley Online Library
Chirality, as one of the most striking characteristics, exists at various scales in nature.
Originating from the interactions of host and guest molecules, supramolecular chirality …

Helicity inversion of supramolecular hydrogels induced by achiral substituents

G Liu, X Li, J Sheng, PZ Li, WK Ong, SZF Phua… - ACS …, 2017 - ACS Publications
Probing the supramolecular chirality of assemblies and controlling their handedness are
closely related to the origin of chirality at the supramolecular level and the development of …

Handedness Inversion of Chiral 3‐Aminophenol Formaldehyde Resin Nanotubes Mediated by Metal Coordination

X Zha, Y Chen, H Fan, Y Yang, Y Xiong… - Angewandte Chemie …, 2021 - Wiley Online Library
Precise adjustment of microstructure and handedness of chiral nanomaterials is important to
regulate their properties and performance. Herein, helical 3‐aminophenol formaldehyde …