Corroles at work: A small macrocycle for great applications

C Di Natale, CP Gros, R Paolesse - Chemical Society Reviews, 2022 - pubs.rsc.org
Corrole chemistry has witnessed an impressive boost in studies in the last 20 years, thanks
to the possibility of preparing corrole derivatives by simple synthetic procedures. The …

Electronic structure of corrole derivatives: insights from molecular structures, spectroscopy, electrochemistry, and quantum chemical calculations

A Ghosh - Chemical Reviews, 2017 - ACS Publications
Presented herein is a comprehensive account of the electronic structure of corrole
derivatives. Our knowledge in this area derives from a broad range of methods, including UV …

Development of a colorimetric and turn-on fluorescent probe with large Stokes shift for H2S detection and its multiple applications in environmental, food analysis and …

G Lu, L Duan, S Meng, P Cai, S Ding, X Wang - Dyes and Pigments, 2023 - Elsevier
A new colorimetric and turn-on fluorescent probe NPC-H 2 S with a large Stokes shift (227
nm) was designed and synthesized for the detection of hydrogen sulfide (H 2 S) in …

Creation from Confusion and Fusion in the Porphyrin World─ The Last Three Decades of N-Confused Porphyrinoid Chemistry

M Toganoh, H Furuta - Chemical Reviews, 2022 - ACS Publications
Confusion is a novel concept of isomerism in porphyrin chemistry, delivering a steady
stream of new chemistry since the discovery of N-confused porphyrin, a porphyrin mutant, in …

Milestones in corrole chemistry: historical ligand syntheses and post-functionalization

A Kumar, D Kim, S Kumar, A Mahammed… - Chemical Society …, 2023 - pubs.rsc.org
Corroles are synthetic porphyrin analogs that contain one meso carbon atom lesser and
bear a trianionic N4 metal-chelating core. They require in-depth preparative chemistry …

Expanded porphyrins: intriguing structures, electronic properties, and reactivities

S Saito, A Osuka - Angewandte Chemie International Edition, 2011 - Wiley Online Library
The chemistry of expanded porphyrins, which are higher homologues of porphyrins, has
been intensively explored for the last three decades. Expanded porphyrins exhibit …

Synthesis of corroles and their heteroanalogs

R Orłowski, D Gryko, DT Gryko - Chemical Reviews, 2017 - ACS Publications
Corroles have come a long way from being a curiosity to being a mainstream research topic.
They are now regularly synthesized in numerous research laboratories worldwide with …

Strategies for corrole functionalization

JFB Barata, MGPMS Neves, MAF Faustino… - Chemical …, 2017 - ACS Publications
This review covers the functionalization reactions of meso-arylcorroles, both at the inner
core, as well as the peripheral positions of the macrocycle. Experimental details for the …

Molecular Engineering of Corrole Radicals by Polycyclic Aromatic Fusion: Towards Open‐Shell Near‐Infrared Materials for Efficient Photothermal Therapy

H Gao, X Zhi, F Wu, Y Zhao, F Cai, P Li… - Angewandte …, 2023 - Wiley Online Library
Open‐shell radicals are promising near‐infrared (NIR) photothermal agents (PTAs) owing to
their easily accessible narrow band gaps, but their stabilization and functionalization remain …

A Corrole‐Based Covalent Organic Framework Featuring Desymmetrized Topology

Y Zhao, W Dai, Y Peng, Z Niu, Q Sun… - Angewandte Chemie …, 2020 - Wiley Online Library
Herein, for the first time, we present the successful synthesis of a novel two‐dimensional
corrole‐based covalent organic framework (COF) by reacting the unusual approximately T …