New high Tc multiferroics KBiFe2O5 with narrow band gap and promising photovoltaic effect

G Zhang, H Wu, G Li, Q Huang, C Yang, F Huang… - Scientific reports, 2013 - nature.com
Intrinsic polarization of ferroelectrics (FE) helps separate photon-generated charge carriers
thus enhances photovoltaic effects. However, traditional FE with transition-metal cations (M) …

Tailored brownmillerite oxide catalyst with multiple electronic functionalities enables ultrafast water oxidation

Y Zhu, HA Tahini, J Zhou, Y Chen, Q Lin… - Chemistry of …, 2021 - ACS Publications
A sluggish oxygen evolution reaction (OER) is a central issue for many chemical and energy
transformation technologies, necessitating the development of cost-effective electrocatalysts …

Crystal structure and electronic properties of bulk and thin film brownmillerite oxides

J Young, JM Rondinelli - Physical Review B, 2015 - APS
The equilibrium structure and functional properties exhibited by brownmillerite oxides, a
family of perovskite-derived structures with alternating layers of BO 6 octahedra and BO 4 …

Enhanced catalytic activity and stability of the oxygen evolution reaction on tetravalent mixed metal oxide

I Yamada, M Kinoshita, S Oda, H Tsukasaki… - Chemistry of …, 2020 - ACS Publications
The oxygen evolution reaction (OER) is a crucial energy conversion reaction for achieving a
sustainable society. Highly active OER catalysts were reported in Fe–Co mixed oxides such …

Brownmillerite‐type Ca2FeCoO5 as a Practicable Oxygen Evolution Reaction Catalyst

E Tsuji, T Motohashi, H Noda, D Kowalski… - …, 2017 - Wiley Online Library
Here, we report remarkable oxygen evolution reaction (OER) catalytic activity of
brownmillerite (BM)‐type Ca2FeCoO5. The OER activity of this oxide is comparable to or …

Unraveling the Role of Structural Order in the Transformation of Electrical Conductivity in Ca2FeCoO6−δ, CaSrFeCoO6−δ, and Sr2FeCoO6−δ

RK Hona, A Huq, F Ramezanipour - Inorganic Chemistry, 2017 - ACS Publications
The ability to control the electrical conductivity of solid-state oxides using structural
parameters has been demonstrated. A correlation has been established between the …

Polar oxides without inversion symmetry through vacancy and chemical order

J Young, EJ Moon, D Mukherjee, G Stone… - Journal of the …, 2017 - ACS Publications
One synthetic modality for materials discovery proceeds by forming mixtures of two or more
compounds. In transition metal oxides (TMOs), chemical substitution often obeys Vegard's …

Electrochemical behavior of oxygen-deficient double perovskite, Ba2FeCoO6-δ, synthesized by facile wet chemical process

A Kumar, A Kumar - Ceramics International, 2019 - Elsevier
New oxygen-deficient double perovskites, Ba 2 FeCoO 6-δ, was prepared using facile wet
chemical route. The synthesized material was characterized by powder X-ray diffraction …

Activation of Catalytically Active Edge-Sharing Domains in Ca2FeCoO5 for Oxygen Evolution Reaction in Highly Alkaline Media

D Kowalski, H Kiuchi, T Motohashi, Y Aoki… - … applied materials & …, 2019 - ACS Publications
Rechargeable zinc–air batteries are considered as one of the possible candidates to
replace conventional lithium-ion batteries. One of the requirements for effective battery …

Transformation of Structure, Electrical Conductivity, and Magnetism in AA′Fe2O6−δ, A = Sr, Ca and A′ = Sr

RK Hona, A Huq, S Mulmi, F Ramezanipour - Inorganic Chemistry, 2017 - ACS Publications
The ability to control electrical properties and magnetism by varying the crystal structure
using the effect of the A-site cation in oxygen-deficient perovskites has been studied in AA …