Joint kinetics: A new paradigm for chemical kinetics and chemical engineering

GS Yablonsky, D Constales, GB Marin - Current Opinion in Chemical …, 2020 - Elsevier
Joint kinetics, a new paradigm for chemical kinetics and chemical engineering, is proposed.
Its main idea is performing a battery of kinetic experiments from special initial compositions …

New invariant expressions in chemical kinetics

GS Yablonsky, D Branco, GB Marin, D Constales - Entropy, 2020 - mdpi.com
This paper presents a review of our original results obtained during the last decade. These
results have been found theoretically for classical mass-action-law models of chemical …

Exact autonomous invariants of nonlinear chemical reactions

NI Kol'tsov - Kinetics and Catalysis, 2020 - Springer
The exact autonomous (time-independent) kinetic invariants of nonlinear chemical reactions
occurring in open systems with the participation of an independent and any number of …

Conservation laws for chemical reactions with nonideal kinetics in a nonisothermal gradient-free reactor

NI Kol'tsov - Russian Journal of Physical Chemistry B, 2022 - Springer
A method for establishing linear conservation laws from the data of nonstationary
experiments for chemical reactions proceeding according to the nonideal kinetic laws (KLs) …

Perturbed and unperturbed: analyzing the conservatively perturbed equilibrium (linear case)

Y Xi, X Liu, D Constales, GS Yablonsky - Entropy, 2020 - mdpi.com
The “conservatively perturbed equilibrium”(CPE) technique for a complex chemical system
is computationally analyzed in a batch reactor considering different linear mechanisms with …

Experimental verification of conservatively perturbed equilibrium for a complex non-linear chemical reaction

B Peng, X Zhu, D Constales, GS Yablonsky - Chemical Engineering …, 2021 - Elsevier
The phenomenon of ''conservatively perturbed equilibrium''(CPE) for a complex non-linear
chemical system was experimentally verified in a batch reactor in which ethanol and benzyl …

Autonomous kinetic invariants of linear chemical reactions

VK Fedotov, NI Kol'tsov - Kinetics and Catalysis, 2019 - Springer
A method has been developed for calculating the exact autonomous kinetic invariants of
multistage linear chemical reactions occurring in a gradientless isothermal reactor via any …

Quasi-invariants of chemical reactions in the ideal displacement reactor

NI Koltsov - Theoretical Foundations of Chemical Engineering, 2020 - Springer
Mathematical models of nonequilibrium processes in distributed systems are described by
partial differential equations with given boundary conditions and, as a rule, cannot be solved …

Conservatively Perturbed Equilibrium (CPE)—Phenomenon as a Tool for Intensifying the Catalytic Process: The Case of Methane Reforming Processes

MO Vilboi, VR Trishch, GS Yablonsky - Catalysts, 2024 - mdpi.com
The phenomenon of conservatively perturbed equilibrium (CPE) was applied to the
processes of methane reforming (dry and steam reforming) and analyzed using kinetic …

Nonlinear kinetic conservation laws in nonlinear chemical reactions

NI Kol'tsov - Russian Journal of Physical Chemistry B, 2021 - Springer
A method is developed for establishing new nonlinear kinetic conservation laws in chemical
reactions proceeding in an open isothermal gradientless reactor according to nonlinear …