The electronic structure of biradicals is characterized by the presence of two unpaired
electrons in degenerate or near‐degenerate molecular orbitals. In particular, some of the …

Photoionization of reactive intermediates with synchrotron radiation has reached a
sufficiently advanced stage of development that it can now contribute to a number of areas in …

In this work, we report rovibrational energy levels for four isotopologues of methylene (CH2,
CHD, CD2, and 13CH2) in their ground triplet electronic state (X~ 3 B 1) from variational …

Mass-selective threshold photoelectron spectroscopy in the gas phase was employed to
characterize the dialkynyl triplet carbenes pentadiynylidene (HC5H) …

Chemical processing in the stratospheres of the gas giants is driven by incident vacuum
ultraviolet (VUV) light. Ethane is an important constituent in the atmospheres of the gas …

We present the absolute photoionization cross-section of the mercapto radical, SH, recorded
from its first ionization energy at 10.4 eV up to a photon energy of 15 eV. The absolute scale …

We studied the thermal decomposition of dimethyl carbonate (DMC, C3H6O3) in a flash
vacuum pyrolysis reactor in the 1100–1700 K range. The reaction products and …

The photoionization of phenylnitrene was investigated by photoion mass-selected threshold
photoelectron spectroscopy in the gas phase. Flash vacuum pyrolysis of phenyl azide at …

The evolution of matter in astrophysical environments, such as the interstellar medium, is
governed by complex chemical processes involving numerous stable and radical species in …

Photoionization of reactive intermediates with synchrotron radiation has reached a
sufficiently advanced stage of development that it can now contribute to a number of areas in …