The chemistry of nitrogen-centered radicals (NCRs) has plentiful applications in organic
synthesis, and they continue to expand as our understanding of these reactive species …

Organoboron compounds are versatile synthons in synthetic chemistry, materials science,
and medicinal chemistry. The preparation of them often requires either reactive …

A photoredox-catalyzed 1, 2-amidoheteroarylation of unactivated alkenes with O-acyl
hydroxylamine derivatives and heterocycles is presented. A range of heterocycles, including …

The photoinitiated deaminative [3+ 2] annulation reaction of N-aminopyridinium salts with
alkenes for the synthesis of functionalized γ-lactams is described. This transformation shows …

A photo-induced transition-metal-free regioselective hydroborylation of α, β-unsaturated
carbonyl compounds is developed. The PhSSPh reagent was employed as the …

A detailed study of iminyl radical cyclizations of O-aryloximes tethered to alkenes is reported.
The reactions can be triggered by either microwave irradiation or conventional heating in an …

Three-component 1, 2-carboamination of vinyl boronic esters with alkyl/aryl lithium reagents
and N-chloro-carbamates/carboxamides is presented. Vinylboron ate complexes generated …

Benzocyclic boronates have attracted increasing research interest in drug chemistry and
organic synthesis in recent years. Herein, we report a facile access to benzocyclic boronates …

Air‐stable amine‐and phosphine‐boranes are discovered as donors to integrate with
pyridinium acceptor for generating photoactive electron‐donor‐acceptor (EDA) complexes …

We report the intramolecular 1, n-aminoboration for the simultaneous synthesis of aza-
heterocycles with distal carbon–boron bonds. Pd-catalyzed remote 1, n-aminoboration …