(Hetero)aryl‐SVI Fluorides: Synthetic Development and Opportunities

M Magre, S Ni, J Cornella - Angewandte Chemie International …, 2022 - Wiley Online Library
Abstract (Hetero) arylsulfur compounds where the S atom is in the oxidation state VI
represent a large percentage of the molecular functionalities present in organic chemistry …

Chemistry of Pentafluorosulfanyl Derivatives and Related Analogs: From Synthesis to Applications

R Kordnezhadian, BY Li, A Zogu… - … A European Journal, 2022 - Wiley Online Library
Abstract Pentafluorosulfanyl (SF5)‐containing compounds and corresponding analogs are a
highly valuable class of fluorine‐containing building blocks owing to their unique properties …

Recent advances on visible light pyrrole-derived photoinitiators of polymerization

F Dumur - European Polymer Journal, 2022 - Elsevier
Photopolymerization is the focus of intense research efforts due to the recent need to
develop visible light photoinitiating systems activable under low light intensity and in the …

A Facile Molecular Machine: Optically Triggered Counterion Migration by Charge Transfer of Linear Donor‐π‐Acceptor Phosphonium Fluorophores

A Belyaev, YH Cheng, ZY Liu… - Angewandte Chemie …, 2019 - Wiley Online Library
The D‐π‐A type phosphonium salts in which electron acceptor (A=‐+ PR3) and donor (D=‐
NPh2) groups are linked by polarizable π‐conjugated spacers show intense fluorescence …

Photoredox Catalytic Pentafluorosulfanylative Domino Cyclization of α‐Substituted Alkenes to Oxaheterocycles by Using SF6

D Rombach, B Birenheide… - Chemistry–A European …, 2021 - Wiley Online Library
Virtually inert sulfur hexafluoride becomes a precious pentafluorosulfanylation agent, if
properly activated by photoredox catalysis, to access α‐fluoro and α‐alkoxy SF5 …

Pentafluorosulfanyl group: an emerging tool in optoelectronic materials

JMW Chan - Journal of Materials Chemistry C, 2019 - pubs.rsc.org
The pentafluorosulfanyl (SF5) moiety is a lesser known and underutilized functional group
that displays high electronegativity, chemical and thermal stability, and low surface energy …

Suitability of alkyne donor-π-donor-π-donor scaffolds for electrofluorochromic and electrochromic use

M Wałęsa-Chorab, K Muras, HL Filiatrault… - Journal of Materials …, 2022 - pubs.rsc.org
A series of electroactive materials consisting of an aromatic core that was conjugated with
two alkynes and flanked with two triphenyl amines was investigated as electrochromes and …

Donor acceptor fluorophores: synthesis, optical properties, TD-DFT and cytotoxicity studies

ZM Essam, GE Ozmen, D Setiawan… - Organic & …, 2021 - pubs.rsc.org
Donor–π-acceptor (D–π-A) fluorophores consisting of a donor unit, a π linker, and an
acceptor moiety have attracted attention in the last decade. In this study, we report the …

Photochemical Activation of Sulfur Hexafluoride: A Tool for Fluorination and Pentafluorosulfanylation Reactions

D Rombach, HA Wagenknecht - Synthesis, 2022 - thieme-connect.com
The photoactivation of notoriously inert sulfur hexafluoride represents a challenge for
photochemistry. This short review summarizes recently published efforts and the …

Pentafluorosulfanyl-functionalised BODIPY push–pull dyes for p-type dye-sensitized solar cells

RD James, LS Alqahtani, J Mallows, HV Flint… - Sustainable Energy & …, 2023 - pubs.rsc.org
We report a push–pull BODIPY-based dye functionalised with an electronegative SF5 group
at the meso position for applications in photocathodes in tandem dye-sensitized solar cells …