Supramolecular helical systems: helical assemblies of small molecules, foldamers, and polymers with chiral amplification and their functions
E Yashima, N Ousaka, D Taura, K Shimomura… - Chemical …, 2016 - ACS Publications
In this review, we describe the recent advances in supramolecular helical assemblies
formed from chiral and achiral small molecules, oligomers (foldamers), and helical and …
formed from chiral and achiral small molecules, oligomers (foldamers), and helical and …
Supramolecular chirality in self-assembled systems
M Liu, L Zhang, T Wang - Chemical reviews, 2015 - ACS Publications
Chirality is a basic characteristic of living matter and nature. During the evolution of life on
our planet, nature has favored one kind of chirality, thereby selecting the l-amino acids (with …
our planet, nature has favored one kind of chirality, thereby selecting the l-amino acids (with …
[HTML][HTML] Stimuli-responsive synthetic helical polymers
M Lago-Silva, M Fernández-Míguez… - Chemical Society …, 2024 - pubs.rsc.org
Synthetic dynamic helical polymers (supramolecular and covalent) and foldamers share the
helix as a structural motif. Although the materials are different, these systems also share …
helix as a structural motif. Although the materials are different, these systems also share …
Circularly polarized luminescence polymers: From design to applications
S Yang, S Zhang, F Hu, J Han, F Li - Coordination Chemistry Reviews, 2023 - Elsevier
Circularly polarized luminescence (CPL) materials have received extensive interest due to
their unique optical activity. An increasing number of research endeavors were focused on …
their unique optical activity. An increasing number of research endeavors were focused on …
Helical polymers: synthesis, structures, and functions
The helix is the central structural motif in biological macromolecules, such as DNA and
proteins, and is also the ubiquitous object in nature from microscopic to macroscopic points …
proteins, and is also the ubiquitous object in nature from microscopic to macroscopic points …
Super-assembled chiral mesostructured heteromembranes for smart and sensitive couple-accelerated enantioseparation
In the context of sustainable development, chirality, especially chiral drugs, has attracted
great interest in the pharmaceutical industry, yet the smart and sensitive separation of …
great interest in the pharmaceutical industry, yet the smart and sensitive separation of …
Helical polymers with dynamic and static macromolecular helicity memory: The power of helicity memory for helical polymer synthesis and applications
E Yashima, K Maeda - Bulletin of the Chemical Society of Japan, 2021 - academic.oup.com
In this Account, we describe the recent progress in the synthesis and unique features and
functions of helical polymers with a controlled handedness based on the noncovalent …
functions of helical polymers with a controlled handedness based on the noncovalent …
Switchable enantioseparation based on macromolecular memory of a helical polyacetylene in the solid state
In the chromatographic separation of enantiomers the order of elution is determined by the
strength of diasteromeric interactions between the components of the mixture and a chiral …
strength of diasteromeric interactions between the components of the mixture and a chiral …
Control of dynamic helicity at the macro-and supramolecular level
D Pijper, BL Feringa - Soft Matter, 2008 - pubs.rsc.org
In this review, various systems developed in recent years which aim to control dynamic
helicity at the macro-and supramolecular level are discussed. The strong interactions …
helicity at the macro-and supramolecular level are discussed. The strong interactions …
Unexpectedly strong chiral amplification of chiral/achiral and chiral/chiral copolymers of biphenylylacetylenes and further enhancement/inversion and memory of the …
R Ishidate, AJ Markvoort, K Maeda… - Journal of the American …, 2019 - ACS Publications
We report an unexpectedly strong amplification of the macromolecular helicity in dynamic
helical copolymers of chiral/achiral and chiral/chiral (R/S) biphenylylacetylenes in which the …
helical copolymers of chiral/achiral and chiral/chiral (R/S) biphenylylacetylenes in which the …