Molecular metal phosphonates
J Goura, V Chandrasekhar - Chemical reviews, 2015 - ACS Publications
The carboxylate ligand,[RCO 2]−, is one of the most versatile and hence also one of the most
ubiquitous ligands in coordination chemistry.(1-4) Although fairly simple coordination modes …
ubiquitous ligands in coordination chemistry.(1-4) Although fairly simple coordination modes …
Phosphonate based high nuclearity magnetic cages
JA Sheikh, HS Jena, A Clearfield… - Accounts of Chemical …, 2016 - ACS Publications
Conspectus Transition metal based high nuclearity molecular magnetic cages are a very
important class of compounds owing to their potential applications in fabricating new …
important class of compounds owing to their potential applications in fabricating new …
Probing the Origin of Ferro-/Antiferromagnetic Exchange Interactions in Cu (II)–4f Complexes
The mechanistic investigations between Cu (II) and the anisotropic lanthanides (Ln (III)) are
not much explored to date. This is due to the complicated energy spectrum which arises due …
not much explored to date. This is due to the complicated energy spectrum which arises due …
Theoretical Studies on Hexanuclear [M3(μ3-O/OH)]2 (M = Fe(III), Mn(III), and Ni(II)) Clusters: Magnetic Exchange, Magnetic Anisotropy, and Magneto-Structural …
MK Singh, G Rajaraman - Inorganic chemistry, 2019 - ACS Publications
Controlling spin Hamiltonian parameters such as magnetic exchange and magnetic
anisotropy of polynuclear clusters is of great interest in the area of single molecule magnets …
anisotropy of polynuclear clusters is of great interest in the area of single molecule magnets …
Modulation of magnetic anisotropy and exchange interaction in phenoxide-bridged dinuclear co (II) complexes
We report a new class of four dimeric Co (II) complexes [Co2 (bbpen)(X) 2](H2bbpen= N,
N′-bis (2-hydroxybenzyl)-N, N′-bis (2-methylpyridyl) ethylenediamine)[X–= SCN (1), Cl …
N′-bis (2-hydroxybenzyl)-N, N′-bis (2-methylpyridyl) ethylenediamine)[X–= SCN (1), Cl …
An S-Shaped [Fe4Dy2] Complex Exhibiting Slow Relaxation of Magnetization: Synthesis, Magnetism, and Crystal Structures of a Family of [Fe4Ln2][Ln] …
A series of heterobimetallic 3d− 4f cluster coordination compounds has been synthesized
using a Schiff-base ligand (H3L), a trinuclear iron (III) precursor complex and lanthanide …
using a Schiff-base ligand (H3L), a trinuclear iron (III) precursor complex and lanthanide …
Generalized Synthesis of Calixarene-Based High-Nuclearity M4n Nanocages (M = Ni or Co; n = 2–6)
A family of high-nuclearity M4 n (M= Ni or Co, n= 2–6) coordination nanocages constructed
by M4–calix [4] arene molecular building blocks (MBBs) with inorganic phosphate or organic …
by M4–calix [4] arene molecular building blocks (MBBs) with inorganic phosphate or organic …
Measuring Metal–Metal Communication in a Series of Ketimide-Bridged [Fe2]6+ Complexes
PR Hertler, RA Lewis, G Wu, TW Hayton - Inorganic Chemistry, 2023 - ACS Publications
Reaction of Fe (acac) 3 with 3 equiv of Li [N═ C (R) Ph](R= Ph, t Bu) results in the formation
of the [Fe2] 6+ complexes,[Fe2 (μ-N═ C (R) Ph) 2 (N═ C (R) Ph) 4](R= Ph, 1; t Bu, 2), in low …
of the [Fe2] 6+ complexes,[Fe2 (μ-N═ C (R) Ph) 2 (N═ C (R) Ph) 4](R= Ph, 1; t Bu, 2), in low …
Hexanuclear and undecanuclear iron (III) carboxylates as catalyst precursors for cyclohexane oxidation
MNM Milunovic, LM Martins, ECBA Alegria… - Dalton …, 2013 - pubs.rsc.org
Two multinuclear complexes [Fe6 (μ3-O) 2 (μ4-O2) L10 (OAc) 2 (H2O) 2]· 2.625 Et2O· 2.375
H2O (1) and [FeIII11Cl (μ4-O) 3 (μ3-O) 5L16 (dmf) 2.5 (H2O) 0.5]· Et2O· 1.25 dmf· 3.8 H2O …
H2O (1) and [FeIII11Cl (μ4-O) 3 (μ3-O) 5L16 (dmf) 2.5 (H2O) 0.5]· Et2O· 1.25 dmf· 3.8 H2O …
Coordination induced fluorescence enhancement and construction of a Zn 3 constellation through hydrolysis of ligand imine arms
The phenoxido and alkoxido bridged neutral Zn3 complex [Zn3 (μ-H2bemp) 2 (μ3-emp)
2](1), with an angular Zn3 (μ-OPh) 2 (μ-OEt) 2 core and capping nitrogen donors, was …
2](1), with an angular Zn3 (μ-OPh) 2 (μ-OEt) 2 core and capping nitrogen donors, was …